Magnetic tape cartridge and magnetic tape apparatus

ABSTRACT

The magnetic tape cartridge includes a magnetic tape that is accommodated in the magnetic tape cartridge while being wound around a reel hub. A water absorption amount of the magnetic tape measured after the magnetic tape cartridge is stored in a storage environment of a temperature of 32° C. and a relative humidity of 80% for 10 days is 0.30 g or less as a value in terms of a length of the magnetic tape of 1000 m, and the water absorption amount is a value measured in a measurement environment with a temperature of 21° C. and a relative humidity of 50% within 1 hour after the storage.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims priority under 35 U.S.C 119 to Japanese PatentApplication No. 2020-124710 filed on Jul. 21, 2020. The aboveapplication is hereby expressly incorporated by reference, in itsentirety, into the present application.

BACKGROUND OF THE INVENTION 1. Field of the Invention

The present invention relates to a magnetic tape cartridge and amagnetic tape apparatus.

2. Description of the Related Art

There are two types of magnetic recording media: a tape shape and a diskshape, and a tape-shaped magnetic recording medium, that is, a magnetictape is mainly used for data storage applications such as data backupand archiving (for example, see JP2012-43495A).

SUMMARY OF THE INVENTION

Recording of data on a magnetic tape and reproduction of data recordedon the magnetic tape are usually performed as follows.

The magnetic tape is run in a magnetic tape apparatus. A surface(specifically, a surface of a magnetic layer) of the running magnetictape and a magnetic head are brought into contact with each other to beslid on each other, whereby the magnetic head records data on themagnetic tape and/or reproduces data recorded on the magnetic tape.

Usually, the magnetic tape is shipped as a product in a state of beingaccommodated in a magnetic tape cartridge and is stored in such a stateuntil it is used in the magnetic tape apparatus. In addition, themagnetic tape after the data is recorded is usually stored in a state ofbeing accommodated in the magnetic tape cartridge. The storage may beperformed in a storage environment where temperature and humidity arenot controlled, or in a storage environment where temperature andhumidity are not strictly controlled.

With respect to this, the recording of data on the magnetic tape and/orthe reproduction of data recorded on the magnetic tape may be performedin a data center where temperature and humidity are more strictlycontrolled than in the storage environment.

Under such circumstances, as a use form of the magnetic tape, there maybe a use form in which, after the magnetic tape is taken out from astorage environment with high temperature and high humidity, therecording of data on the magnetic tape and/or the reproduction of datarecorded on the magnetic tape is performed in a data center wheretemperature and humidity are significantly lower than those in thestorage environment within a short period of time. In such a use form, ahigh friction coefficient in a case where the magnetic tape and themagnetic head are slid on each other causes lowering of runningstability. Therefore, in order to improve the running stability in theabove-described use form, it is desirable that the magnetic tapeaccommodated in the magnetic tape cartridge has excellent frictioncharacteristics in a state of being exposed to a large change intemperature and humidity (specifically, environmental change from a hightemperature and high humidity environment to an environment with lowertemperature and humidity) within a short period of time.

In view of the above description, an object of an aspect of the presentinvention is to provide a magnetic tape cartridge comprising a magnetictape having excellent friction characteristics in a state of beingexposed to the above-described large change in temperature and humiditywithin a short period of time.

An aspect of the present invention relates to a magnetic tape cartridgecomprising a magnetic tape that is accommodated in the magnetic tapecartridge while being wound around a reel hub, in which a waterabsorption amount of the magnetic tape measured after the magnetic tapecartridge is stored in a storage environment of a temperature of 32° C.and a relative humidity of 80% for 10 days is 0.30 g or less as a valuein terms of a length of the magnetic tape of 1000 m, and the waterabsorption amount is a value measured in a measurement environment witha temperature of 21° C. and a relative humidity of 50% within 1 hourafter the storage.

In one embodiment, the water absorption amount may be 0.10 g or more and0.30 g or less.

In one embodiment, the magnetic tape may have a non-magnetic support anda magnetic layer including a ferromagnetic powder, and the non-magneticsupport may be a polyester support.

In one embodiment, the magnetic tape may further have a non-magneticlayer including a non-magnetic powder between the non-magnetic supportand the magnetic layer.

In one embodiment, the magnetic tape may further have a back coatinglayer including a non-magnetic powder on a surface side of thenon-magnetic support opposite to a surface side having the magneticlayer.

In one embodiment, a tape thickness of the magnetic tape may be 5.6 μmor less.

In one embodiment, a tape thickness of the magnetic tape may be 5.3 μmor less.

Another aspect of the present invention relates to a magnetic tapeapparatus comprising the magnetic tape cartridge.

According to an aspect of the present invention, it is possible toprovide a magnetic tape cartridge comprising a magnetic tape havingexcellent friction characteristics in a state of being exposed toenvironmental change from a high temperature and high humidityenvironment to an environment with lower temperature and humidity withina short period of time. In addition, according to an aspect of thepresent invention, it is possible to provide a magnetic tape apparatusincluding such a magnetic tape cartridge.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a perspective view of an example of a magnetic tape cartridge.

FIG. 2 is a perspective view in a case where a magnetic tape is startedto be wound around a reel.

FIG. 3 is a perspective view in a case where the winding of the magnetictape around the reel is completed.

FIG. 4 is an explanatory diagram of an edge weave.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

Magnetic Tape Cartridge

An aspect of the present invention relates to a magnetic tape cartridgein which a magnetic tape is accommodated while being wound around a reelhub. A water absorption amount of the magnetic tape measured after themagnetic tape cartridge is stored in a storage environment of atemperature of 32° C. and a relative humidity of 80% for 10 days is 0.30g or less as a value in terms of a length of the magnetic tape of 1000m. Here, the water absorption amount is a value measured in ameasurement environment with a temperature of 21° C. and a relativehumidity of 50% within 1 hour after the storage, and also simplyreferred to as a “water absorption amount” below. Unless otherwisenoted, in the present invention and the present specification, thetemperature related to the environment is referred to as an atmospheretemperature of such an environment.

Regarding friction characteristics of the magnetic tape, it has beenconventionally considered that the friction characteristics tend todecrease in a high temperature and high humidity environment, whereasthe friction characteristics tend to improve in an environment withlower temperature and humidity. However, according to the study by thepresent inventor, there has been found a phenomenon in which, in a casewhere a magnetic tape cartridge comprising a magnetic tape is used forrecording or reproducing data in an environment with lower temperatureand humidity within a short period of time after being stored in a hightemperature and high humidity environment, the friction characteristicsof the magnetic tape are lowered. The present inventor considered that acause of occurrence of such a phenomenon is that the magnetic tapeabsorbs a large amount of moisture in the magnetic tape cartridge in ahigh temperature and high humidity environment. The present inventorsupposes that in a case where the magnetic tape cartridge is used in astate where the magnetic tape absorbs a large amount of moisture withouta period in which the moisture is sufficiently dehydrated, even though ause environment is a low temperature and low humidity environmentcompared to a storage environment, a large shearing force acts between amagnetic tape surface and a magnetic head due to the influence of themoisture, thereby lowering the friction characteristics. As a result offurther intensive studies, the present inventor have newly found that ina case where the water absorption amount of the magnetic tape in theabove storage environment is in the range, excellent frictioncharacteristics are obtained in the use in an environment with lowertemperature and humidity than the storage environment. The temperatureand humidity of the storage environment are employed as an example ofhigh temperature and high humidity, and an environment in which themagnetic tape cartridge is stored is not limited to the storageenvironment. In addition, the reason why the water absorption amount ismeasured within 1 hour after storage is intended to obtain a valuecorresponding to a state of the magnetic tape in a case of being usedwithin a short period of time after storage. The temperature andhumidity of the measurement environment are employed as an example ofvalues lower than the temperature and humidity of the storageenvironment with high temperature and high humidity, and an environmentin which the magnetic tape cartridge is used is not limited to themeasurement environment.

Water Absorption Amount

The water absorption amount in the present invention and the presentspecification is obtained by the following method.

For the measurement, an unused magnetic tape cartridge that is notmounted on the magnetic tape apparatus is used.

A total of two rolls of the unused magnetic tape cartridge are prepared.These two rolls of magnetic tape cartridge can be magnetic tapecartridges manufactured in the same formulation and under the sameconditions, or can be two rolls randomly extracted from the same lot ofproducts or products of the same product name. It is acceptable thatthere are errors that can normally occur in a manufacturing process forthe same formulation and the same conditions as described above.

From one of the two rolls of magnetic tape cartridge, the magnetic tapeaccommodated therein is pulled out and removed. This magnetic tapecartridge is called a “tapeless cartridge”. The other roll of magnetictape cartridge is left in a state where the magnetic tape isaccommodated therein. This magnetic tape cartridge is called a“tape-containing cartridge”. For the tapeless cartridge, in a case wherethere is an accessory (for example, a pin and a splicing tape) that isconnected to the magnetic tape, the accessory is also pulled out fromthe magnetic tape cartridge with the magnetic tape and removed. Inobtaining the water absorption amount of the magnetic tape by using thetape-containing cartridge and the tapeless cartridge as shown below, theinfluence of the water absorption of the accessory on the waterabsorption amount is nil or negligible, and therefore no considerationis required.

The tape-containing cartridge and the tapeless cartridge are placed in ameasurement environment with a temperature of 21° C. and a relativehumidity of 50% for 5 days or more and allowed to acclimatize to themeasurement environment. After 5 days or more, the mass of the magnetictape cartridge is measured in the same measurement environment. The massof the tape-containing cartridge measured here is defined as “A1”, andthe mass of the tapeless cartridge is defined as “B1”.

The tape-containing cartridge and the tapeless cartridge after the abovemeasurement are stored in a storage environment with a temperature of32° C. and a relative humidity of 80% for 10 days.

Within 1 hour after the above storage, the mass of the magnetic tapecartridge is measured in a measurement environment with a temperature of21° C. and a relative humidity of 50%. The mass of the tape-containingcartridge measured here is defined as “A2”, and the mass of the tapelesscartridge is defined as “B2”.

A water absorption amount X of the tape-containing cartridge iscalculated as “X=A2−A1”.

A water absorption amount Y of the tapeless cartridge is calculated as“Y=B2−B1”.

A value “X−Y” obtained by subtracting Y from X can be referred to as awater absorption amount of the magnetic tape accommodated in themagnetic tape cartridge. From the value “X−Y” and the total length L(unit: m) of the magnetic tape accommodated in the magnetic tapecartridge, a conversion value of the water absorption amount per 1000 mof the length of the magnetic tape is obtained as “((X−Y)×1000)/L”.Here, for a magnetic tape including portions other than a recording areasuch as a leader tape, the total length L of the magnetic tape is alength including the portions.

For the tape-containing cartridge, A1 and A2 are measured three times bythe above method. An arithmetic average of the water absorption amount(conversion value per 1000 m of the length of the magnetic tape)obtained in this way is defined as the water absorption amount of themagnetic tape measured in terms of the length of 1000 m after themagnetic tape cartridge is stored in a storage environment of atemperature of 32° C. and a relative humidity of 80% for 10 days.

The water absorption amount can be referred to as an index of a degreeof water absorption of the magnetic tape in a state of beingaccommodated in the magnetic tape cartridge. The fact that the waterabsorption amount measured for the magnetic tape cartridge is 0.30 g orless can contribute to obtaining excellent friction characteristics in astate of being exposed to environmental change from a high temperatureand high humidity environment to an environment with lower temperatureand humidity within a short period of time. From this point, the waterabsorption amount is 0.30 g or less, and more preferably 0.20 g or less.In addition, the water absorption amount may be, for example, 0 g, 0 gor more, more than 0 g, or 0.10 g or more. The smaller the value of thewater absorption amount is, the more preferable it is from the viewpointof improving the friction characteristics. The means for controlling thewater absorption amount will be described below.

Hereinafter, the magnetic tape cartridge will be described in moredetail.

Configuration of Magnetic Tape Cartridge

In the magnetic tape cartridge, the magnetic tape is accommodated insidea cartridge body in a state of being wound around a reel hub. The reelof the magnetic tape cartridge is configured of at least a reel hub, andusually, flanges are provided at both ends of the reel hub. The reel isrotatably provided inside the cartridge body. As the magnetic tapecartridge, a single reel type magnetic tape cartridge having one reelinside the cartridge body and a dual reel type magnetic tape cartridgehaving two reels inside the cartridge body are widely used. In a casewhere the single reel type magnetic tape cartridge is mounted on amagnetic tape apparatus for recording and/or reproducing data on themagnetic tape, the magnetic tape is pulled out of the magnetic tapecartridge to be wound around the reel on the magnetic tape apparatusside. A magnetic head is disposed on a magnetic tape transportation pathfrom the magnetic tape cartridge to a winding reel. Feeding and windingof the magnetic tape are performed between a reel (supply reel) on themagnetic tape cartridge and a reel (winding reel) on the magnetic tapeapparatus. During this time, data is recorded and/or reproduced as themagnetic head and the magnetic layer surface of the magnetic tape comeinto contact with each other to be slid on each other. With respect tothis, in the dual reel type magnetic tape cartridge, both reels of thesupply reel and the winding reel are provided in the magnetic tapecartridge. The magnetic tape cartridge is a single reel type magnetictape cartridge in an aspect, and a dual reel type magnetic tapecartridge in another aspect. In an aspect, the magnetic tape cartridgeis preferably a single reel type magnetic tape cartridge that has beenmainly employed in the data storage field in recent years.

A configuration example of the magnetic tape cartridge will be describedbelow with reference to the drawings. However, one embodiments shown inthe drawings are examples, and the present invention is not limited tosuch examples.

FIG. 1 is a perspective view of an example of the magnetic tapecartridge. FIG. 1 shows a single reel type magnetic tape cartridge.

A magnetic tape cartridge 10 shown in FIG. 1 has a case 12. The case 12is formed in a rectangular box shape. The case 12 is usually made of aresin such as polycarbonate. Only one reel 20 is rotatably accommodatedinside the case 12.

FIG. 2 is a perspective view in a case where the magnetic tape isstarted to be wound around a reel. FIG. 3 is a perspective view in acase where the winding of the magnetic tape around the reel iscompleted.

The reel 20 has a reel hub 22. The reel hub is a cylindrical memberconstituting a shaft center part around which the magnetic tape is woundin the magnetic tape cartridge.

Flanges (lower flange 24 and upper flange 26) projecting outward in aradial direction from a lower end and an upper end of the reel hub 22are provided at both ends of the reel hub 22. Here, regarding “upper”and “lower”, in a case where the magnetic tape cartridge is mounted onthe magnetic tape apparatus, the side located above is referred to as“upper” and the side located below is referred to as “lower”. One orboth of the lower flange 24 and the upper flange 26 are preferablyconfigured integrally with the reel hub 22 from the viewpoint ofreinforcing the upper end side and/or the lower end side of the reel hub22. The term “configured integrally with” means that it is configurednot as a separate member but as one member. In a first aspect, the reelhub 22 and the upper flange 26 are configured as one member, and thismember is joined to the lower flange 24 configured as a separate memberby a well-known method. In a second aspect, the reel hub 22 and thelower flange 24 are configured as one member, and this member is joinedto the upper flange 26 configured as a separate member by a well-knownmethod. The reel of the magnetic tape cartridge may be in any aspect.Each member can be manufactured by a well-known molding method such asinjection molding.

A magnetic tape T is wound around an outer periphery of the reel hub 22starting from a tape inner end Tf (see FIG. 2 ). The higher the tensionapplied in the longitudinal direction of the magnetic tape (hereinafter,also referred to as a “winding tension”) in a case where the magnetictape is wound around the reel hub, the tighter the magnetic tape can bewound around the reel hub. It is considered that the tighter themagnetic tape is wound around the reel hub, the narrower the gap betweenone surface and the other surface of the magnetic tape in contact witheach other in the wound state, or the less likely the gap is to occur.It is supposed that this makes it possible to prevent moisture fromentering through the gap and the magnetic tape from absorbing water. Thewinding tension is preferably 0.60 N (Newton) or more, more preferably0.80 N or more, and still more preferably 1.00 N or more. In addition,the winding tension may be, for example, 2.00 N or less or 1.80 N orless. The tension applied in the longitudinal direction of the magnetictape described in the present specification is a set value set by atension control mechanism.

An opening 14 for pulling out the magnetic tape T wound around the reel20 is provided in a side wall of the case 12, and a leader pin 16 to bepulled out while being locked by a pull-out member (not shown) of themagnetic tape apparatus (not shown) is fixed to a tape outer end Te ofthe magnetic tape T pulled out from the opening 14.

The opening 14 is opened and closed by a door 18. The door 18 is formedin a shape of a rectangular plate having a size capable of closing theopening 14, and is urged by an urging member (not shown) in a directionof closing the opening 14. In a case where the magnetic tape cartridge10 is mounted on the magnetic tape apparatus, the door 18 is openedagainst an urging force of the urging member.

The above aspect is an example, and a well-known technology can beapplied to the details of the magnetic tape cartridge. The total lengthof the magnetic tape accommodated in the magnetic tape cartridge is notparticularly limited, and may be in a range of, for example, about 800 mto 2500 m. The longer the total length of the tape accommodated in oneroll of the magnetic tape cartridge, the more preferable it is from theviewpoint of increasing the capacity of the magnetic tape cartridge.

Magnetic Layer

Ferromagnetic Powder

The magnetic tape accommodated in the magnetic tape cartridge can have anon-magnetic support and a magnetic layer including a ferromagneticpowder. As the ferromagnetic powder included in the magnetic layer, awell-known ferromagnetic powder as a ferromagnetic powder used inmagnetic layers of various magnetic recording media can be used alone orin combination of two or more. From the viewpoint of improving recordingdensity, it is preferable to use a ferromagnetic powder having a smallaverage particle size. From this point, the average particle size of theferromagnetic powder is preferably 50 nm or less, more preferably 45 nmor less, still more preferably 40 nm or less, still more preferably 35nm or less, still more preferably 30 nm or less, still more preferably25 nm or less, and still more preferably 20 nm or less. On the otherhand, from the viewpoint of magnetization stability, the averageparticle size of the ferromagnetic powder is preferably 5 nm or more,more preferably 8 nm or more, still more preferably 10 nm or more, stillmore preferably 15 nm or more, and still more preferably 20 nm or more.

Hexagonal Ferrite Powder

Preferred specific examples of the ferromagnetic powder include ahexagonal ferrite powder. For details of the hexagonal ferrite powder,for example, descriptions disclosed in paragraphs 0012 to 0030 ofJP2011-225417A, paragraphs 0134 to 0136 of JP2011-216149A, paragraphs0013 to 0030 of JP2012-204726A, and paragraphs 0029 to 0084 ofJP2015-127985A can be referred to.

In the present invention and the present specification, the term“hexagonal ferrite powder” refers to a ferromagnetic powder in which ahexagonal ferrite type crystal structure is detected as a main phase byX-ray diffraction analysis. The main phase refers to a structure towhich the highest intensity diffraction peak in an X-ray diffractionspectrum obtained by X-ray diffraction analysis is attributed. Forexample, in a case where the highest intensity diffraction peak isattributed to a hexagonal ferrite type crystal structure in an X-raydiffraction spectrum obtained by X-ray diffraction analysis, it isdetermined that the hexagonal ferrite type crystal structure is detectedas the main phase. In a case where only a single structure is detectedby X-ray diffraction analysis, this detected structure is taken as themain phase. The hexagonal ferrite type crystal structure includes atleast an iron atom, a divalent metal atom, and an oxygen atom, as aconstituent atom. The divalent metal atom is a metal atom that can be adivalent cation as an ion, and examples thereof may include an alkalineearth metal atom such as a strontium atom, a barium atom, and a calciumatom, and a lead atom. In the present invention and the presentspecification, a hexagonal strontium ferrite powder refers to a powderin which a main divalent metal atom is a strontium atom, and a hexagonalbarium ferrite powder refers to a powder in which a main divalent metalatom is a barium atom. The main divalent metal atom refers to a divalentmetal atom that accounts for the most on an at % basis among thedivalent metal atoms included in the powder. Here, a rare earth atom isnot included in the above divalent metal atom. The term “rare earthatom” in the present invention and the present specification is selectedfrom the group consisting of a scandium atom (Sc), an yttrium atom (Y),and a lanthanoid atom. The Lanthanoid atom is selected from the groupconsisting of a lanthanum atom (La), a cerium atom (Ce), a praseodymiumatom (Pr), a neodymium atom (Nd), a promethium atom (Pm), a samariumatom (Sm), a europium atom (Eu), a gadolinium atom (Gd), a terbium atom(Tb), a dysprosium atom (Dy), a holmium atom (Ho), an erbium atom (Er),a thulium atom (Tm), an ytterbium atom (Yb), and a lutetium atom (Lu).

Hereinafter, the hexagonal strontium ferrite powder, which is an aspectof the hexagonal ferrite powder, will be described in more detail.

An activation volume of the hexagonal strontium ferrite powder ispreferably in a range of 800 to 1600 nm³. The finely granulatedhexagonal strontium ferrite powder having an activation volume in theabove range is suitable for manufacturing a magnetic tape exhibitingexcellent electromagnetic conversion characteristics. The activationvolume of the hexagonal strontium ferrite powder is preferably 800 nm³or more, and may be, for example, 850 nm³ or more. Further, from theviewpoint of further improving the electromagnetic conversioncharacteristics, the activation volume of the hexagonal strontiumferrite powder is more preferably 1500 nm³ or less, still morepreferably 1400 nm³ or less, still more preferably 1300 nm³ or less,still more preferably 1200 nm³ or less, and still more preferably 1100nm³ or less. The same applies to an activation volume of the hexagonalbarium ferrite powder.

The “activation volume” is a unit of magnetization reversal and is anindex indicating the magnetic size of a particle. An activation volumedescribed in the present invention and the present specification and ananisotropy constant Ku which will be described below are values obtainedfrom the following relational expression between a coercivity Hc and anactivation volume V, by performing measurement in a coercivity Hcmeasurement portion at a magnetic field sweep rate of 3 minutes and 30minutes using a vibrating sample magnetometer (measurement temperature:23° C.±1° C.). For a unit of the anisotropy constant Ku, 1erg/cc=1.0×10⁻¹ J/m³.Hc=2Ku/Ms{1−[(kT/KuV)In(At/0.693)]^(1/2)}

[In the above formula, Ku: anisotropy constant (unit: J/m³), Ms:saturation magnetization (Unit: kA/m), k: Boltzmann constant, T:absolute temperature (unit: K), V: activation volume (unit: cm³), A:spin precession frequency (unit: s⁻¹), t: magnetic field reversal time(unit: s)]

An index for reducing thermal fluctuation, in other words, for improvingthermal stability may include the anisotropy constant Ku. The hexagonalstrontium ferrite powder preferably may have Ku of 1.8×10⁵ J/m³ or more,and more preferably have Ku of 2.0×10⁵ J/m³ or more. Ku of the hexagonalstrontium ferrite powder may be, for example, 2.5×10⁵ J/m³ or less.Here, the higher Ku is, the higher the thermal stability is, which ispreferable, and thus, a value thereof is not limited to the valuesexemplified above.

The hexagonal strontium ferrite powder may or may not include a rareearth atom. In a case where the hexagonal strontium ferrite powderincludes a rare earth atom, it is preferable to include a rare earthatom at a content (bulk content) of 0.5 to 5.0 at % with respect to 100at % of an iron atom. In an aspect, the hexagonal strontium ferritepowder including a rare earth atom may have a rare earth atom surfacelayer portion uneven distribution property. In the present invention andthe present specification, the “rare earth atom surface layer portionuneven distribution property” means that a rare earth atom content withrespect to 100 at % of an iron atom in a solution obtained by partiallydissolving the hexagonal strontium ferrite powder with an acid(hereinafter, referred to as a “rare earth atom surface layer portioncontent” or simply a “surface layer portion content” for a rare earthatom) and a rare earth atom content with respect to 100 at % of an ironatom in a solution obtained by totally dissolving the hexagonalstrontium ferrite powder with an acid (hereinafter, referred to as a“rare earth atom bulk content” or simply a “bulk content” for a rareearth atom) satisfy a ratio of a rare earth atom surface layer portioncontent/a rare earth atom bulk content >1.0. A rare earth atom contentin the hexagonal strontium ferrite powder which will be described belowhas the same meaning as the rare earth atom bulk content. On the otherhand, partial dissolution using an acid dissolves a surface layerportion of a particle constituting the hexagonal strontium ferritepowder, and thus, a rare earth atom content in a solution obtained bypartial dissolution is a rare earth atom content in a surface layerportion of a particle constituting the hexagonal strontium ferritepowder. A rare earth atom surface layer portion content satisfying aratio of “rare earth atom surface layer portion content/rare earth atombulk content >1.0” means that in a particle constituting the hexagonalstrontium ferrite powder, rare earth atoms are unevenly distributed in asurface layer portion (that is, more than an inside). The surface layerportion in the present invention and the present specification means apartial region from a surface of a particle constituting the hexagonalstrontium ferrite powder toward an inside.

In a case where the hexagonal strontium ferrite powder includes a rareearth atom, a rare earth atom content (bulk content) is preferably in arange of 0.5 to 5.0 at % with respect to 100 at % of an iron atom. It isconsidered that a bulk content in the above range of the included rareearth atom and uneven distribution of the rare earth atoms in a surfacelayer portion of a particle constituting the hexagonal strontium ferritepowder contribute to suppression of a decrease in reproduction outputduring repeated reproduction. It is supposed that this is because thehexagonal strontium ferrite powder includes a rare earth atom with abulk content in the above range, and rare earth atoms are unevenlydistributed in a surface layer portion of a particle constituting thehexagonal strontium ferrite powder, and thus it is possible to increasean anisotropy constant Ku. The higher a value of an anisotropy constantKu is, the more a phenomenon called so-called thermal fluctuation can besuppressed (in other words, thermal stability can be improved). Bysuppressing occurrence of thermal fluctuation, it is possible tosuppress a decrease in reproduction output during repeated reproduction.It is supposed that uneven distribution of rare earth atoms in aparticulate surface layer portion of the hexagonal strontium ferritepowder contributes to stabilization of spins of iron (Fe) sites in acrystal lattice of a surface layer portion, and thus, an anisotropyconstant Ku may be increased.

Moreover, it is supposed that the use of the hexagonal strontium ferritepowder having a rare earth atom surface layer portion unevendistribution property as a ferromagnetic powder in the magnetic layeralso contributes to inhibition of a magnetic layer surface from beingscraped by being slid with respect to the magnetic head. That is, it issupposed that the hexagonal strontium ferrite powder having a rare earthatom surface layer portion uneven distribution property can alsocontribute to an improvement of running durability of the magnetic tape.It is supposed that this may be because uneven distribution of rareearth atoms on a surface of a particle constituting the hexagonalstrontium ferrite powder contributes to an improvement of interactionbetween the particle surface and an organic substance (for example, abinding agent and/or an additive) included in the magnetic layer, and,as a result, a strength of the magnetic layer is improved.

From the viewpoint of further suppressing a decrease in reproductionoutput during repeated reproduction and/or the viewpoint of furtherimproving running durability, the rare earth atom content (bulk content)is more preferably in a range of 0.5 to 4.5 at %, still more preferablyin a range of 1.0 to 4.5 at %, and still more preferably in a range of1.5 to 4.5 at %.

The bulk content is a content obtained by totally dissolving thehexagonal strontium ferrite powder. In the present invention and thepresent specification, unless otherwise noted, the content of an atommeans a bulk content obtained by totally dissolving the hexagonalstrontium ferrite powder. The hexagonal strontium ferrite powderincluding a rare earth atom may include only one kind of rare earth atomas the rare earth atom, or may include two or more kinds of rare earthatoms. The bulk content in a case of including two or more types of rareearth atoms is obtained for the total of two or more types of rare earthatoms. This also applies to other components in the present inventionand the present specification. That is, unless otherwise noted, acertain component may be used alone or in combination of two or more. Acontent amount or a content in a case where two or more components areused refers to that for the total of two or more components.

In a case where the hexagonal strontium ferrite powder includes a rareearth atom, the included rare earth atom need only be any one or more ofrare earth atoms. As a rare earth atom that is preferable from theviewpoint of further suppressing a decrease in reproduction outputduring repeated reproduction, there are a neodymium atom, a samariumatom, a yttrium atom, and a dysprosium atom, here, the neodymium atom,the samarium atom, and the yttrium atom are more preferable, and aneodymium atom is still more preferable.

In the hexagonal strontium ferrite powder having a rare earth atomsurface layer portion uneven distribution property, the rare earth atomsneed only be unevenly distributed in the surface layer portion of aparticle constituting the hexagonal strontium ferrite powder, and thedegree of uneven distribution is not limited. For example, for ahexagonal strontium ferrite powder having a rare earth atom surfacelayer portion uneven distribution property, a ratio of a surface layerportion content of a rare earth atom obtained by partial dissolutionunder dissolution conditions which will be described below to a bulkcontent of a rare earth atom obtained by total dissolution underdissolution conditions which will be described below, that is, “surfacelayer portion content/bulk content” exceeds 1.0 and may be 1.5 or more.The fact that “surface layer portion content/bulk content” is largerthan 1.0 means that in a particle constituting the hexagonal strontiumferrite powder, rare earth atoms are unevenly distributed in the surfacelayer portion (that is, more than an inside). Further, a ratio of asurface layer portion content of a rare earth atom obtained by partialdissolution under dissolution conditions which will be described belowto a bulk content of a rare earth atom obtained by total dissolutionunder the dissolution conditions which will be described below, that is,“surface layer portion content/bulk content” may be, for example, 10.0or less, 9.0 or less, 8.0 or less, 7.0 or less, 6.0 or less, 5.0 orless, or 4.0 or less. Here, in the hexagonal strontium ferrite powderhaving a rare earth atom surface layer portion uneven distributionproperty, the rare earth atoms need only be unevenly distributed in thesurface layer portion of a particle constituting the hexagonal strontiumferrite powder, and “surface layer portion content/bulk content” is notlimited to the exemplified upper limit or lower limit.

The partial dissolution and the total dissolution of the hexagonalstrontium ferrite powder will be described below. For the hexagonalstrontium ferrite powder that exists as a powder, the partially andtotally dissolved sample powder is taken from the same lot of powder. Onthe other hand, for the hexagonal strontium ferrite powder included inthe magnetic layer of the magnetic tape, a part of the hexagonalstrontium ferrite powder taken out from the magnetic layer is subjectedto partial dissolution, and the other part is subjected to totaldissolution. The hexagonal strontium ferrite powder can be taken outfrom the magnetic layer by a method described in a paragraph 0032 ofJP2015-91747A, for example.

The partial dissolution means that dissolution is performed such that,at the end of dissolution, the residue of the hexagonal strontiumferrite powder can be visually confirmed in the solution. For example,by partial dissolution, it is possible to dissolve a region of 10 to 20mass % of the particle constituting the hexagonal strontium ferritepowder with the total particle being 100 mass %. On the other hand, thetotal dissolution means that dissolution is performed such that, at theend of dissolution, the residue of the hexagonal strontium ferritepowder cannot be visually confirmed in the solution.

The partial dissolution and measurement of the surface layer portioncontent are performed by the following method, for example. Here, thefollowing dissolution conditions such as the amount of sample powder areexemplified, and dissolution conditions for partial dissolution andtotal dissolution can be employed in any manner.

A container (for example, a beaker) containing 12 mg of the samplepowder and 10 mL of 1 mol/L hydrochloric acid is held on a hot plate ata set temperature of 70° C. for 1 hour. The obtained solution isfiltered by a membrane filter of 0.1 μm. Elemental analysis of thefiltrated solution is performed by an inductively coupled plasma (ICP)analyzer. In this way, the surface layer portion content of a rare earthatom with respect to 100 at % of an iron atom can be obtained. In a casewhere a plurality of types of rare earth atoms are detected by elementalanalysis, the total content of all rare earth atoms is defined as thesurface layer portion content. This also applies to the measurement ofthe bulk content.

On the other hand, the total dissolution and measurement of the bulkcontent are performed by the following method, for example.

A container (for example, a beaker) containing 12 mg of the samplepowder and 10 mL of 4 mol/L hydrochloric acid is held on a hot plate ata set temperature of 80° C. for 3 hours. Thereafter, the same procedureas the partial dissolution and the measurement of the surface layerportion content is carried out, and the bulk content with respect to 100at % of an iron atom can be obtained.

From the viewpoint of increasing the reproduction output in a case ofreproducing data recorded on the magnetic tape, it is desirable thatmass magnetization σs of the ferromagnetic powder included in themagnetic tape is high. In this regard, the hexagonal strontium ferritepowder including a rare earth atom but not having the rare earth atomsurface layer portion uneven distribution property tends to have alarger decrease in σs than that of the hexagonal strontium ferritepowder including no rare earth atom. With respect to this, it isconsidered that the hexagonal strontium ferrite powder having a rareearth atom surface layer portion uneven distribution property ispreferable in suppressing such a large decrease in σs. In an aspect, σsof the hexagonal strontium ferrite powder may be 45 A·m²/kg or more, andmay be 47 A·m²/kg or more. On the other hand, from the viewpoint ofnoise reduction, σs is preferably 80 A·m²/kg or less and more preferably60 A·m²/kg or less. σs can be measured using a well-known measuringdevice, such as a vibrating sample magnetometer, capable of measuringmagnetic properties. In the present invention and the presentspecification, unless otherwise noted, the mass magnetization σs is avalue measured at a magnetic field intensity of 15 kOe. 1[kOe]=10⁶/4π[A/m]

Regarding the content (bulk content) of a constituent atom of thehexagonal strontium ferrite powder, a strontium atom content may be, forexample, in a range of 2.0 to 15.0 at % with respect to 100 at % of aniron atom. In an aspect, the hexagonal strontium ferrite powder mayinclude only a strontium atom as a divalent metal atom. In anotheraspect, the hexagonal strontium ferrite powder may include one or moreother divalent metal atoms in addition to a strontium atom. For example,a barium atom and/or a calcium atom may be included. In a case wheredivalent metal atoms other than a strontium atom are included, a bariumatom content and a calcium atom content in the hexagonal strontiumferrite powder are, for example, in a range of 0.05 to 5.0 at % withrespect to 100 at % of an iron atom.

As a crystal structure of hexagonal ferrite, a magnetoplumbite type(also referred to as an “M-type”), a W-type, a Y-type, and a Z-type areknown. The hexagonal strontium ferrite powder may have any crystalstructure. The crystal structure can be confirmed by X-ray diffractionanalysis. In the hexagonal strontium ferrite powder, a single crystalstructure or two or more crystal structures may be detected by X-raydiffraction analysis. For example, according to an aspect, in thehexagonal strontium ferrite powder, only the M-type crystal structuremay be detected by X-ray diffraction analysis. For example, M-typehexagonal ferrite is represented by a composition formula of AFe₁₂O₁₉.Here, A represents a divalent metal atom, and in a case where thehexagonal strontium ferrite powder is the M-type, A is only a strontiumatom (Sr), or in a case where, as A, a plurality of divalent metal atomsare included, as described above, a strontium atom (Sr) accounts for themost on an at % basis. The divalent metal atom content of the hexagonalstrontium ferrite powder is usually determined by the type of crystalstructure of the hexagonal ferrite and is not particularly limited. Thesame applies to the iron atom content and the oxygen atom content. Thehexagonal strontium ferrite powder may include at least an iron atom, astrontium atom, and an oxygen atom, and may further include a rare earthatom. Furthermore, the hexagonal strontium ferrite powder may or may notinclude atoms other than these atoms. As an example, the hexagonalstrontium ferrite powder may include an aluminum atom (Al). A content ofan aluminum atom may be, for example, 0.5 to 10.0 at % with respect to100 at % of an iron atom. From the viewpoint of further suppressing adecrease in reproduction output during repeated reproduction, thehexagonal strontium ferrite powder includes an iron atom, a strontiumatom, an oxygen atom, and a rare earth atom, and the content of atomsother than these atoms is preferably 10.0 at % or less, more preferablyin a range of 0 to 5.0 at %, and may be 0 at % with respect to 100 at %of an iron atom. That is, in an aspect, the hexagonal strontium ferritepowder may not include atoms other than an iron atom, a strontium atom,an oxygen atom, and a rare earth atom. The content expressed in at % isobtained by converting a content of each atom (unit: mass %) obtained bytotally dissolving the hexagonal strontium ferrite powder into a valueexpressed in at % using an atomic weight of each atom. Further, in thepresent invention and the present specification, the term “not include”for a certain atom means that a content measured by an ICP analyzerafter total dissolution is 0 mass %. A detection limit of the ICPanalyzer is usually 0.01 parts per million (ppm) or less on a massbasis. The term “not included” is used as a meaning including that anatom is included in an amount less than the detection limit of the ICPanalyzer. In an aspect, the hexagonal strontium ferrite powder may notinclude a bismuth atom (Bi).

Metal Powder

Preferred specific examples of the ferromagnetic powder include aferromagnetic metal powder. For details of the ferromagnetic metalpowder, for example, descriptions disclosed in paragraphs 0137 to 0141of JP2011-216149A and paragraphs 0009 to 0023 of JP2005-251351A can bereferred to.

ε-Iron Oxide Powder

Preferred specific examples of the ferromagnetic powder include anε-iron oxide powder. In the present invention and the presentspecification, the term “ε-iron oxide powder” refers to a ferromagneticpowder in which an ε-iron oxide type crystal structure is detected as amain phase by X-ray diffraction analysis. For example, in a case wherethe highest intensity diffraction peak is attributed to an ε-iron oxidetype crystal structure in an X-ray diffraction spectrum obtained byX-ray diffraction analysis, it is determined that the ε-iron oxide typecrystal structure is detected as the main phase. As a method ofmanufacturing the ε-iron oxide powder, a producing method from agoethite, a reverse micelle method, and the like are known. All of themanufacturing methods are well known. Regarding a method ofmanufacturing an ε-iron oxide powder in which a part of Fe issubstituted with substitutional atoms such as Ga, Co, Ti, Al, or Rh, adescription disclosed in J. Jpn. Soc. Powder Metallurgy Vol. 61Supplement, No. 51, pp. 5280 to 5284, J. Mater. Chem. C, 2013, 1, pp.5200 to 5206 can be referred to, for example. Here, the method ofmanufacturing the ε-iron oxide powder capable of being used as theferromagnetic powder in the magnetic layer of the magnetic tape is notlimited to the methods described here.

An activation volume of the ε-iron oxide powder is preferably in a rangeof 300 to 1500 nm³. The finely granulated ε-iron oxide powder having anactivation volume in the above range is suitable for manufacturing amagnetic tape exhibiting excellent electromagnetic conversioncharacteristics. The activation volume of the ε-iron oxide powder ispreferably 300 nm³ or more, and may be, for example, 500 nm³ or more.Further, from the viewpoint of further improving the electromagneticconversion characteristics, the activation volume of the ε-iron oxidepowder is more preferably 1400 nm³ or less, still more preferably 1300nm³ or less, still more preferably 1200 nm³ or less, and still morepreferably 1100 nm³ or less.

An index for reducing thermal fluctuation, in other words, for improvingthermal stability may include the anisotropy constant Ku. The ε-ironoxide powder preferably has Ku of 3.0×10⁴ J/m³ or more, and morepreferably has Ku of 8.0×10⁴ J/m³ or more. Ku of the ε-iron oxide powdermay be, for example, 3.0×10⁵ J/m³ or less. Here, the higher Ku is, thehigher the thermal stability is, which is preferable, and thus, a valuethereof is not limited to the values exemplified above.

From the viewpoint of increasing the reproduction output in a case ofreproducing data recorded on the magnetic tape, it is desirable thatmass magnetization σs of the ferromagnetic powder included in themagnetic tape is high. In this regard, in an aspect, σs of the ε-ironoxide powder may be 8 A·m²/kg or more, and may be 12 A·m²/kg or more. Onthe other hand, from the viewpoint of noise reduction, σs of the ε-ironoxide powder is preferably 40 A·m²/kg or less and more preferably 35A·m²/kg or less.

In the present invention and the present specification, unless otherwisenoted, an average particle size of various powders such as ferromagneticpowders is a value measured by the following method using a transmissionelectron microscope.

The powder is imaged at an imaging magnification of 100,000 using atransmission electron microscope, and the image is printed on printingpaper so that the total magnification is 500,000 to obtain an image ofparticles constituting the powder. A target particle is selected fromthe obtained image of particles, an outline of the particle is traced bya digitizer, and a size of the particle (primary particle) is measured.The primary particle is an independent particle which is not aggregated.

The measurement described above is performed regarding 500 particlesrandomly extracted. An arithmetic average of the particle sizes of 500particles thus obtained is an average particle size of the powder. Asthe transmission electron microscope, a transmission electron microscopeH-9000 manufactured by Hitachi, Ltd. can be used, for example. Inaddition, the measurement of the particle size can be performed bywell-known image analysis software, for example, image analysis softwareKS-400 manufactured by Carl Zeiss. An average particle size shown inExamples which will be described below is a value measured by using atransmission electron microscope H-9000 manufactured by Hitachi, Ltd. asthe transmission electron microscope, and image analysis software KS-400manufactured by Carl Zeiss as the image analysis software, unlessotherwise noted. In the present invention and the present specification,the powder means an aggregate of a plurality of particles. For example,the ferromagnetic powder means an aggregate of a plurality offerromagnetic particles. Further, the aggregate of the plurality ofparticles not only includes an aspect in which particles constitutingthe aggregate directly come into contact with each other, but alsoincludes an aspect in which a binding agent or an additive which will bedescribed below is interposed between the particles. The term “particle”is used to describe a powder in some cases.

As a method of taking a sample powder from the magnetic tape in order tomeasure the particle size, a method disclosed in a paragraph 0015 ofJP2011-048878A can be employed, for example.

In the present invention and the present specification, unless otherwisenoted, (1) in a case where the shape of the particle observed in theparticle image described above is a needle shape, a fusiform shape, or acolumnar shape (here, a height is greater than a maximum long diameterof a bottom surface), the size (particle size) of the particlesconstituting the powder is shown as a length of a long axis configuringthe particle, that is, a long axis length, (2) in a case where the shapeof the particle is a plate shape or a columnar shape (here, a thicknessor a height is smaller than a maximum long diameter of a plate surfaceor a bottom surface), the particle size is shown as a maximum longdiameter of the plate surface or the bottom surface, and (3) in a casewhere the shape of the particle is a sphere shape, a polyhedron shape,or an amorphous shape, and the long axis configuring the particlescannot be specified from the shape, the particle size is shown as anequivalent circle diameter. The equivalent circle diameter is a valueobtained by a circle projection method.

In addition, regarding an average acicular ratio of the powder, a lengthof a short axis, that is, a short axis length of the particles ismeasured in the measurement described above, a value of (long axislength/short axis length) of each particle is obtained, and anarithmetic average of the values obtained regarding the above 500particles is calculated. Here, unless otherwise noted, in a case of (1),the short axis length as the definition of the particle size is a lengthof a short axis configuring the particle, in a case of (2), the shortaxis length is a thickness or a height, and in a case of (3), the longaxis and the short axis are not distinguished, thus, the value of (longaxis length/short axis length) is assumed as 1, for convenience.

In addition, unless otherwise noted, in a case where the shape of theparticle is specified, for example, in a case of definition of theparticle size (1), the average particle size is an average long axislength, and in a case of the definition (2), the average particle sizeis an average plate diameter. In a case of the definition (3), theaverage particle size is an average diameter (also referred to as anaverage particle diameter).

The content (filling percentage) of the ferromagnetic powder of themagnetic layer is preferably in a range of 50 to 90 mass % and morepreferably in a range of 60 to 90 mass %. A high filling percentage ofthe ferromagnetic powder in the magnetic layer is preferable from theviewpoint of improvement of recording density.

Binding Agent

The magnetic tape can be a coating type magnetic tape, and include abinding agent in the magnetic layer. The binding agent is one or moreresins. As the binding agent, various resins usually used as a bindingagent of a coating type magnetic recording medium can be used. Forexample, as the binding agent, a resin selected from a polyurethaneresin, a polyester resin, a polyamide resin, a vinyl chloride resin, anacrylic resin obtained by copolymerizing styrene, acrylonitrile, ormethyl methacrylate, a cellulose resin such as nitrocellulose, an epoxyresin, a phenoxy resin, and a polyvinylalkylal resin such as polyvinylacetal or polyvinyl butyral can be used alone or a plurality of resinscan be mixed with each other to be used. Among these, a polyurethaneresin, an acrylic resin, a cellulose resin, and a vinyl chloride resinare preferable. The resin may be a homopolymer or a copolymer. Theseresins can also be used as the binding agent in a non-magnetic layerand/or a back coating layer which will be described below.

For the above binding agent, descriptions disclosed in paragraphs 0028to 0031 of JP2010-24113A can be referred to. An average molecular weightof the resin used as the binding agent can be, for example, 10,000 ormore and 200,000 or less as a weight-average molecular weight. Theweight-average molecular weight of the present invention and the presentspecification is a value obtained by performing polystyrene conversionof a value measured by gel permeation chromatography (GPC) under thefollowing measurement conditions. A weight-average molecular weight of abinding agent shown in Examples which will be described below is a valueobtained by performing polystyrene conversion of a value measured underthe following measurement conditions. The binding agent can be used inan amount of, for example, 1.0 to 30.0 parts by mass with respect to100.0 parts by mass of the ferromagnetic powder.

GPC device: HLC-8120 (manufactured by Tosoh Corporation)

Column: TSK gel Multipore HXL-M (manufactured by Tosoh Corporation, 7.8mm inner diameter (ID)×30.0 cm)

Eluent: Tetrahydrofuran (THF)

Curing Agent

A curing agent can also be used together with the resin which can beused as the binding agent. As the curing agent, in an aspect, athermosetting compound which is a compound in which curing reaction(crosslinking reaction) proceeds due to heating can be used, and inanother aspect, a photocurable compound in which a curing reaction(crosslinking reaction) proceeds due to light irradiation can be used.Curing reaction proceeds in a magnetic layer forming process, whereby atleast a part of the curing agent can be included in the magnetic layerin a state of being reacted (crosslinked) with other components such asthe binding agent. The same applies to the layer formed using thiscomposition in a case where the composition used to form the other layerincludes a curing agent. The preferred curing agent is a thermosettingcompound, and polyisocyanate is suitable for this. For details of thepolyisocyanate, descriptions disclosed in paragraphs 0124 and 0125 ofJP2011-216149A can be referred to. The curing agent may be used in amagnetic layer forming composition in an amount of, for example, 0 to80.0 parts by mass, and preferably 50.0 to 80.0 parts by mass from aviewpoint of improving a strength of the magnetic layer, with respect to100.0 parts by mass of the binding agent.

Additive

The magnetic layer may include one or more kinds of additives, asnecessary. As the additives, the curing agent described above is used asan example. In addition, examples of the additive which can be includedin the magnetic layer include a non-magnetic powder (for example, aninorganic powder or carbon black), a lubricant, a dispersing agent, adispersing assistant, an antibacterial agent, an antistatic agent, anantioxidant, and the like. For example, for the lubricant, descriptionsdisclosed in paragraphs 0030 to 0033, 0035, and 0036 of JP2016-126817Acan be referred to. The non-magnetic layer described below may include alubricant. For the lubricant which may be included in the non-magneticlayer, descriptions disclosed in paragraphs 0030, 0031, and 0034 to 0036of JP2016-126817A can be referred to. For the dispersing agent,descriptions disclosed in paragraphs 0061 and 0071 of JP2012-133837A canbe referred to. The dispersing agent may be added to a non-magneticlayer forming composition. For the dispersing agent that can be added tothe non-magnetic layer forming composition, a description disclosed in aparagraph 0061 of JP2012-133837A can be referred to. As the non-magneticpowder that can be included in the magnetic layer, a non-magnetic powderwhich can function as an abrasive, or a non-magnetic powder which canfunction as a protrusion forming agent which forms protrusions suitablyprotruded from the magnetic layer surface (for example, non-magneticcolloidal particles) is used. An average particle size of colloidalsilica (silica colloidal particle) shown in examples described below isa value obtained by a method disclosed in a paragraph 0015 ofJP2011-048878A as a method for measuring an average particle diameter.As the additive, a commercially available product can be suitablyselected or manufactured by a well-known method according to the desiredproperties, and any amount thereof can be used. Examples of the additivethat can be used to improve the dispersibility of the abrasive in themagnetic layer containing the abrasive include a dispersing agentdisclosed in paragraphs 0012 to 0022 of JP2013-131285A.

The magnetic layer described above can be provided directly on a surfaceof the non-magnetic support or indirectly through the non-magneticlayer.

Non-Magnetic Layer

Next, the non-magnetic layer will be described. The above magnetic tapemay have a magnetic layer directly on the surface of the non-magneticsupport, or may have a magnetic layer on the surface of the non-magneticsupport through a non-magnetic layer including a non-magnetic powder.The non-magnetic powder used for the non-magnetic layer may be aninorganic substance powder or an organic substance powder. In addition,carbon black and the like can be used. Examples of the inorganicsubstance powder include powders of metal, metal oxide, metal carbonate,metal sulfate, metal nitride, metal carbide, and metal sulfide. Thenon-magnetic powder can be purchased as a commercially available productor can be manufactured by a well-known method. For details thereof,descriptions disclosed in paragraphs 0146 to 0150 of JP2011-216149A canbe referred to. For carbon black which can be used in the non-magneticlayer, descriptions disclosed in paragraphs 0040 and 0041 ofJP2010-24113A can be referred to. The content (filling percentage) ofthe non-magnetic powder of the non-magnetic layer is preferably in arange of 50 to 90 mass % and more preferably in a range of 60 to 90 mass%.

The non-magnetic layer can include a binding agent, and can also includean additive. For other details of the binding agent or the additive ofthe non-magnetic layer, a well-known technology regarding thenon-magnetic layer can be applied. In addition, in regards to the typeand the content of the binding agent, and the type and the content ofthe additive, for example, a well-known technology regarding themagnetic layer can be applied.

In the present invention and the present specification, the non-magneticlayer also includes a substantially non-magnetic layer including a smallamount of ferromagnetic powder as impurities, for example, orintentionally, together with the non-magnetic powder. Here, thesubstantially non-magnetic layer refers to a layer having a residualmagnetic flux density of 10 mT or less, a coercivity of 7.96 kA/m (100Oe) or less, or a residual magnetic flux density of 10 mT or less and acoercivity of 7.96 kA/m (100 Oe) or less. It is preferable that thenon-magnetic layer does not have a residual magnetic flux density and acoercivity.

Back Coating Layer

The magnetic tape may or may not have a back coating layer including anon-magnetic powder on a surface side of the non-magnetic supportopposite to a surface side provided with the magnetic layer. Preferably,the back coating layer contains one or both of carbon black and aninorganic powder. The back coating layer can include a binding agent,and can also include an additive. In regards to the binding agent andthe additive of the back coating layer, the well-known technologyregarding the back coating layer can be applied, and the well-knowntechnology regarding the formulation of the magnetic layer and/or thenon-magnetic layer can be applied. For example, for the back coatinglayer, descriptions disclosed in paragraphs 0018 to 0020 ofJP2006-331625A and column 4, line 65 to column 5, line 38 of U.S. Pat.No. 7,029,774B can be referred to.

Non-Magnetic Support

Examples of the non-magnetic support (hereinafter, simply referred to asa “support”) include well-known components such as polyethyleneterephthalate, polyethylene naphthalate, polyamide, polyamideimide, andaromatic polyamide. Among these, polyethylene terephthalate andpolyethylene naphthalate are preferable.

In an aspect, the non-magnetic support of the magnetic tape can be apolyester support. In the present invention and the presentspecification, the term “polyester” means a resin containing a pluralityof ester bonds. The term “polyester support” means a support containingat least one layer of polyester film. The term “polyester film” refersto a film in which a component that occupies the largest amount on amass basis among components constituting the film is a polyester. Theterm “polyester support” in the present invention and the presentspecification includes those in which all resin films contained in thesupport are polyester films, and those containing the polyester film andanother resin film. Specific aspects of the polyester support include asingle-layer polyester film, a laminated film of two or more polyesterfilms having the same constituent components, a laminated film of two ormore polyester films having different constituent components, alaminated film including one or more polyester films and one or moreresin films other than the polyester film, and the like. An adhesivelayer or the like may be optionally included between two adjacent layersin the laminated film. The polyester support may optionally include ametal film and/or a metal oxide film formed on one or both surfaces byvapor deposition or the like. The same applies to an “aromatic polyestersupport”, a “polyethylene terephthalate support”, and a “polyethylenenaphthalate support” in the present invention and the presentspecification.

The polyester support can be an aromatic polyester support. In thepresent invention and the present specification, the term “aromaticpolyester” means a resin containing an aromatic skeleton and a pluralityof ester bonds, and the “aromatic polyester support” means a supportcontaining at least one aromatic polyester film.

An aromatic ring contained in the aromatic skeleton of the aromaticpolyester is not particularly limited. Specific examples of the aromaticring include a benzene ring and a naphthalene ring.

For example, polyethylene terephthalate (PET) is a polyester containinga benzene ring, and is a resin obtained by polycondensing ethyleneglycol with terephthalic acid and/or dimethyl terephthalate. The term“polyethylene terephthalate” in the present invention and the presentspecification includes those having a structure having one or more othercomponents (for example, a copolymer component, a component introducedinto a terminal or a side chain, or the like) in addition to the abovecomponent.

Polyethylene naphthalate (PEN) is a polyester containing a naphthalenering, and is a resin obtained by performing an esterification reactionbetween dimethyl 2,6-naphthalenedicarboxylate and ethylene glycol andthen performing a transesterification reaction and a polycondensationreaction. The term “polyethylene naphthalate” in the present inventionand the present specification includes those having a structure havingone or more other components (for example, a copolymer component, acomponent introduced into a terminal or a side chain, or the like) inaddition to the above component.

The non-magnetic support may be a biaxially stretched film, and may be afilm that has been subjected to corona discharge, a plasma treatment, aneasy-bonding treatment, a heat treatment, or the like.

As an index of the physical properties of the non-magnetic support, forexample, a moisture content can be used. In the present invention andthe present specification, a moisture content of the non-magneticsupport is a value obtained by the following method. The moisturecontent shown in the table below is a value obtained by the followingmethod.

A sample piece (for example, a sample piece having a mass of a fewgrams) cut out from the non-magnetic support of which the moisturecontent is to be measured is dried in a vacuum dryer at a temperature of180° C. and a pressure of 100 Pa (Pascal) or less until the sample piecehas a constant weight. A mass of the sample piece thus dried is definedas W1. W1 is a value measured in a measurement environment of atemperature of 23° C. and a relative humidity of 50% within 30 secondsafter the sample piece is taken out from the vacuum dryer. Next, a massof this sample piece after being left under an environment of atemperature of 25° C. and a relative humidity of 75% for 48 hours isdefined as W2. W2 is a value measured in a measurement environment of atemperature of 23° C. and a relative humidity of 50% within 30 secondsafter the sample piece is taken out from the environment. The moisturecontent is calculated by the following equation.Moisture content (%)=[(W2−W1)/W1]×100For example, after removing portions, such as the magnetic layer, otherthan the non-magnetic support from the magnetic tape by a well-knownmethod (for example, film removal using an organic solvent), themoisture content of the non-magnetic support can be obtained by theabove method.

The non-magnetic support of the magnetic tape preferably has a moisturecontent of 0.80% or less, and more preferably has a moisture content of0.60% or less. In addition, the moisture content of the non-magneticsupport of the magnetic tape may be 0%, 0% or more, more than 0%, or0.10% or more. The present inventor supposes that the use of anon-magnetic support having a low moisture content obtained by the abovemethod can contribute to reduction of the value of the water absorptionamount obtained by the method described above for the magnetic tapecartridge.

As an index of the physical properties of the non-magnetic support, forexample, a Young's modulus can be used. In the present invention and thepresent specification, the Young's modulus of the non-magnetic supportis a value to be measured by the following method in a measurementenvironment with a temperature of 23° C. and a relative humidity of 50%.The Young's modulus shown in the table below is a value obtained by thefollowing method using Tensilon manufactured by Toyo Baldwin Co., Ltd.as a universal tensile test device.

A sample piece cut out from the non-magnetic support to be measured ispulled by a universal tensile test device under the conditions of adistance between chucks of 100 mm, a tensile speed of 10 mm/min, and achart speed of 500 mm/min. As the universal tensile test device, forexample, a commercially available universal tensile test device such asTensilon manufactured by Toyo Baldwin Co., Ltd. or a universal tensiletest device having a well-known configuration can be used. Young'smoduli in a longitudinal direction and a width direction of the samplepiece are calculated from a tangent line of a rising portion of aload-elongation curve thus obtained. Here, the longitudinal directionand the width direction of the sample piece mean a longitudinaldirection and a width direction in a case where the sample piece isincluded in the magnetic tape.

For example, after removing portions, such as the magnetic layer, otherthan the non-magnetic support from the magnetic tape by a well-knownmethod (for example, film removal using an organic solvent), the Young'smoduli in the longitudinal direction and the width direction of thenon-magnetic support can be obtained by the above method.

In an aspect, the non-magnetic support of the magnetic tape may have aYoung's modulus in the longitudinal direction of, for example, 3000 MPaor more, 5000 MPa or more, or 7000 MPa or more. In addition, the Young'smodulus of the non-magnetic support of the magnetic tape in thelongitudinal direction may be, for example, 15000 MPa or less, 13000 MPaor less, or 11000 MPa or less. For the width direction, the non-magneticsupport of the magnetic tape may have a Young's modulus in the widthdirection of, for example, 2000 MPa or more, 3000 MPa or more, or 4000MPa or more. In addition, the Young's modulus of the non-magneticsupport of the magnetic tape in the width direction may be, for example,10000 MPa or less, 8000 MPa or less, or 6000 MPa or less. In a casewhere the magnetic tape is manufactured, the non-magnetic support isusually used in a machine direction (MD direction) as the longitudinaldirection and a transverse direction (TD direction) as the widthdirection of the film. In an aspect, the Young's modulus in thelongitudinal direction is greater than the Young's modulus in the widthdirection, in another aspect, the Young's modulus in the longitudinaldirection is smaller than the Young's modulus in the width direction,and in another aspect, the Young's modulus in the longitudinal directionand the Young's modulus in the width direction are the same value.

The moisture content and the Young's modulus of the non-magnetic supportcan be controlled by the types and mixing ratios of the componentsconstituting the support, the manufacturing conditions of the support,and the like. For example, in a biaxial stretching treatment, theYoung's modulus in the longitudinal direction and the Young's modulus inthe width direction can be controlled by adjusting a stretching ratio ineach direction.

Various Thicknesses

Regarding a thickness (total thickness) of the magnetic tape, it hasbeen required to increase the recording capacity (increase the capacity)of the magnetic tape with the enormous increase in the amount ofinformation in recent years. For example, as means for increasing thecapacity, a thickness of the magnetic tape may be reduced (hereinafter,also referred to as “thinning”) to increase a length of the magnetictape accommodated in one roll of a magnetic tape cartridge. From thispoint, the thickness (total thickness) of the magnetic tape ispreferably 5.6 μm or less, more preferably 5.5 μm or less, still morepreferably 5.4 μm or less, still more preferably 5.3 μm or less, andstill more preferably 5.2 μm or less. In addition, from the viewpoint ofease of handling, the thickness of the magnetic tape is preferably 3.0μm or more, and more preferably 3.5 μm or more.

The thickness (total thickness) of the magnetic tape can be measured bythe following method.

Ten tape samples (for example, 5 to 10 cm in length) are cut out fromany part of the magnetic tape, and these tape samples are stacked tomeasure the thickness. A value (thickness per tape sample) obtained bydividing the measured thickness by 1/10 is defined as the tapethickness. The thickness measurement can be performed using a well-knownmeasuring device capable of measuring the thickness on the order of 0.1μm.

A thickness of the non-magnetic support is preferably 3.0 to 5.0 μm.

A thickness of the magnetic layer can be optimized according to asaturation magnetization amount, a head gap length, and a band of arecording signal of the used magnetic head, and is generally 0.01 μm to0.15 μm, and from a viewpoint of high-density recording, is preferably0.02 μm to 0.12 μm, and more preferably 0.03 μm to 0.1 μm. The magneticlayer need only be at least a single layer, the magnetic layer may beseparated into two or more layers having different magnetic properties,and a configuration of a well-known multilayered magnetic layer can beapplied as the magnetic layer. A thickness of the magnetic layer in acase where the magnetic layer is separated into two or more layers is atotal thickness of the layers.

A thickness of the non-magnetic layer is, for example, 0.1 to 1.5 μm,and preferably 0.1 to 1.0 μm.

A thickness of the back coating layer is preferably 0.9 μm or less, andmore preferably 0.1 to 0.7 μm.

Various thicknesses such as the thickness of the magnetic layer can beobtained by the following method.

A cross section of the magnetic tape in a thickness direction is exposedby an ion beam, and then the exposed cross section observation isperformed using a scanning electron microscope. Various thicknesses canbe obtained as an arithmetic average of thicknesses obtained at twooptional points in the cross section observation. Alternatively, thevarious thicknesses can be obtained as a designed thickness calculatedaccording to manufacturing conditions.

Edge Weave Amount

In an aspect, the water absorption amount obtained for the magnetic tapecartridge can be controlled by the edge weave amount of the magnetictape.

The edge weave amount and a cycle of the edge weave will be describedbelow.

FIG. 4 is an explanatory diagram of the edge weave. FIG. 4 schematicallyshows tape edges 1 a and 1 b of the magnetic tape T by partiallyenlarging the tape edge 1 a. In FIG. 4 , an X1-X2 direction is thelongitudinal direction of the magnetic tape and can also be referred toas the running direction. A Y1-Y2 direction is the width direction ofthe magnetic tape. The tape edge of the magnetic tape may have wavyirregularities (irregularities of a shape in which an end surface in thewidth direction of the magnetic tape is wavy along the longitudinaldirection) called an edge weave (or edge wave). The edge weave amount (ain FIG. 4 ) of the edge weave is measured by an edge weave amountmeasuring device over 50 m in the longitudinal direction of a randomlyselected region of the tape edge 1 a or 1 b. In addition, the cycle (fin FIG. 4 ) of the edge weave can be obtained by performing Fourieranalysis on the measured edge weave amount. As the edge weave amountmeasuring device, a commercially available edge weave amount measuringdevice (for example, manufactured by Keyence Corporation) can be used.The measurement environment is an environment with an atmospheretemperature of 23° C. and a relative humidity of 50%. The magnetic tapeis generally distributed while being accommodated in the magnetic tapecartridge. As the magnetic tape to be measured, a magnetic tape takenout from an unused magnetic tape cartridge that is not attached to themagnetic tape apparatus is used.

The edge weave amount of the tape edge on at least on side of themagnetic tape is preferably 1.5 μm or less, more preferably 1.4 μm orless, still more preferably 1.3 μm or less, and still more preferably1.2 μm or less, from the viewpoint of reducing the value of the waterabsorption amount. It is considered that the tighter the magnetic tapeis wound around the reel hub, the narrower the gap between one surfaceand the other surface of the magnetic tape in contact with each other inthe wound state, or the less likely the gap is to occur. It is supposedthat this makes it possible to prevent moisture from entering throughthe gap and the magnetic tape from absorbing water. In this regard, thepresent inventor considers that a small edge weave amount is preferablefor tightly winding the magnetic tape around the reel hub in a casewhere the magnetic tape is wound around the reel hub. On the other hand,from the viewpoint of suppressing a deterioration of electromagneticconversion characteristics after long-term storage, the edge weaveamount is preferably 0.1 μm or more, more preferably 0.3 μm or more,still more preferably 0.6 μm or more, and still more preferably 0.8 μmor more. The tape edge having an edge weave amount in the above rangecan be a tape edge on only one side of the magnetic tape, or can be atape edge on both sides of the magnetic tape. For example, usually, inthe magnetic tape, the position of the magnetic tape in the widthdirection can be regulated by an inner surface of a flange of a guideroller provided in the magnetic tape apparatus. In a case where the tapeedge whose position in the width direction is regulated in this way iscalled a “running reference side tape edge”, it is preferable that theedge weave amount in the running reference side tape edge is in theabove range. In addition, as the magnetic tape apparatus, there is alsoan apparatus having a configuration in which the positions of the tapeedges on both sides of the magnetic tape in the width direction of themagnetic tape are regulated, and in such an apparatus, both tape edgeson both sides can be called a running reference side tape edge.

In addition, from the viewpoint of suppressing a deterioration ofelectromagnetic conversion characteristics after long-term storage, thecycle of the edge weave in which the edge weave amount is in the aboverange is preferably 130.0 mm or less, more preferably 100.0 mm or less,and still more preferably 80.0 mm or less. From this point, the cycle ispreferably 65.0 mm or more, more preferably 70.0 mm or more, and stillmore preferably 80.0 mm or more. The cycle of the edge weave and theedge weave amount can be controlled by a slit condition in a case ofmanufacturing the magnetic tape and the like. For the control method,descriptions disclosed in a paragraph 0030 of JP2002-269711A andExamples of the same publication can also be referred to.

Manufacturing Process

Preparation of Each Layer Forming Composition

A process of preparing a composition for forming the magnetic layer, thenon-magnetic layer, or the back coating layer can generally include atleast a kneading process, a dispersing process, and a mixing processprovided before and after these processes as necessary. Each process maybe divided into two or more stages. Components used for the preparationof each layer forming composition may be added at an initial stage or ina middle stage of each process. As a solvent, one kind or two or morekinds of various solvents generally used for manufacturing a coatingtype magnetic recording medium can be used. For the solvent, forexample, a description disclosed in a paragraph 0153 of JP2011-216149Acan be referred to. In addition, each component may be separately addedin two or more processes. For example, a binding agent may be addedseparately in a kneading process, a dispersing process, and a mixingprocess for adjusting a viscosity after dispersion. In order tomanufacture the magnetic tape, a well-known manufacturing technology canbe used in various processes. In the kneading process, an open kneader,a continuous kneader, a pressure kneader, or a kneader having a strongkneading force such as an extruder is preferably used. For details ofthe kneading treatment, descriptions disclosed in JP1989-106338A(JP-H01-106338A) and JP1989-79274A (JP-H01-79274A) can be referred to.As a dispersing device, a well-known dispersing device can be used. Inany stage of preparing each layer forming composition, filtering may beperformed by a well-known method. The filtering can be performed byusing a filter, for example. As the filter used in the filtering, afilter having a pore diameter of 0.01 to 3 μm (for example, filter madeof glass fiber or filter made of polypropylene) can be used, forexample.

Coating Process

The magnetic layer can be formed by directly applying the magnetic layerforming composition onto the surface of the non-magnetic support orperforming multilayer applying of the magnetic layer forming compositionwith the non-magnetic layer forming composition in order or at the sametime. The back coating layer can be formed by applying the back coatinglayer forming composition onto a surface of the non-magnetic supportopposite to a surface having the non-magnetic layer and/or the magneticlayer (or to be provided with the non-magnetic layer and/or the magneticlayer). For details of application for forming each layer, a descriptiondisclosed in a paragraph 0066 of JP2010-231843A can be referred to.

Other Processes

Well-known technologies can be applied to other various processes formanufacturing the magnetic tape. For the various processes, for example,descriptions disclosed in paragraphs 0067 to 0070 of JP2010-231843A canbe referred to. For example, a coating layer of the magnetic layerforming composition can be subjected to an orientation treatment in anorientation zone while the coating layer is in a wet state. For theorientation treatment, the various well-known technologies including adescription disclosed in a paragraph 0052 of JP2010-24113A can be used.For example, a vertical orientation treatment can be performed by awell-known method such as a method using a polar opposing magnet. In theorientation zone, a drying speed of the coating layer can be controlleddepending on a temperature of dry air and an air volume and/or atransportation speed in the orientation zone. Further, the coating layermay be preliminarily dried before the transportation to the orientationzone.

Through various processes, a long magnetic tape original roll can beobtained. The obtained magnetic tape original roll is cut (slit) by awell-known cutter to have a width of the magnetic tape to be woundaround the reel hub of the magnetic tape cartridge. The width isdetermined in accordance with the standard, and is typically ½ inches. ½inches=12.65 mm.

A servo pattern is usually formed on the magnetic tape obtained byslitting. Details of the servo pattern will be described below.

Heat Treatment

In an aspect, the magnetic tape can be a magnetic tape manufacturedthrough the following heat treatment. In addition, in another aspect, itcan be a magnetic tape manufactured without undergoing the followingheat treatment.

As the heat treatment, a magnetic tape that is cut to have a widthdetermined in accordance with a standard by slitting is wound around acore-shaped member and subjected to a heat treatment in a wound state.

In an aspect, the above heat treatment is performed in a state where themagnetic tape is wound around a core-shaped member for heat treatment(hereinafter, referred to as a “winding core for heat treatment”), themagnetic tape after the heat treatment is wound around a cartridge reelof the magnetic tape cartridge, and the magnetic tape cartridge in whichthe magnetic tape is wound around the cartridge reel can bemanufactured.

The winding core for heat treatment can be made of metal, resin, paper,or the like. The material of the winding core for heat treatment ispreferably a material having high rigidity from the viewpoint ofsuppressing occurrence of winding failure such as spoking. From thispoint, the winding core for heat treatment is preferably made of metalor resin. In addition, as an index of rigidity, a flexural modulus ofthe material of the winding core for heat treatment is preferably 0.2GPa (Gigapascal) or more, and more preferably 0.3 GPa or more. On theother hand, since a high-rigidity material is generally expensive, theuse of the winding core for heat treatment made of a material havingrigidity exceeding the rigidity capable of suppressing the occurrence ofwinding failure leads to an increase in cost. Considering the abovepoint, the flexural modulus of the material of the winding core for heattreatment is preferably 250 GPa or less. The flexural modulus is a valuemeasured in accordance with international organization forstandardization (ISO) 178, and the flexural modulus of various materialsis well-known. In addition, the winding core for heat treatment can be asolid or hollow core-shaped member. In a case of the hollow core-shapedmember, a thickness thereof is preferably 2 mm or more from theviewpoint of maintaining rigidity. In addition, the winding core forheat treatment may or may not have a flange.

It is preferable to perform the heat treatment by preparing a magnetictape having a length equal to or longer than a length (hereinafter,referred to as a “final product length”) to be finally accommodated inthe magnetic tape cartridge as the magnetic tape to be wound around thewinding core for heat treatment, and placing the magnetic tape under aheat treatment environment in a state of being wound around the windingcore for heat treatment. The length of the magnetic tape wound aroundthe winding core for heat treatment is equal to or longer than the finalproduct length, and from the viewpoint of ease of winding around thewinding core for heat treatment or the like, the length is preferablyset to “final product length +α”. This a is preferably 5 m or more fromthe viewpoint of ease of winding. The tension in a case of windingaround the winding core for heat treatment is preferably 0.10 N or more.In addition, from the viewpoint of suppressing of occurrence ofexcessive deformation during manufacturing, the tension in a case ofwinding around the winding core for heat treatment is preferably 1.50 Nor less, and more preferably 1.00 N or less. An outer diameter of thewinding core for heat treatment is preferably 20 mm or more, and morepreferably 40 mm or more, from the viewpoint of ease of winding andsuppression of coiling (curling in the longitudinal direction). Inaddition, the outer diameter of the winding core for heat treatment ispreferably 100 mm or less, and more preferably 90 mm or less. A width ofthe winding core for heat treatment need only be equal to or more than awidth of the magnetic tape wound around the winding core. In addition,in a case where the magnetic tape is removed from the winding core forheat treatment after the heat treatment, it is preferable to remove themagnetic tape from the winding core for heat treatment after themagnetic tape and the winding core for heat treatment are sufficientlycooled, in order to prevent the tape from being deformed unintentionallyduring the removal operation. It is preferable that the removed magnetictape is wound around another winding core (referred to as a “temporarywinding core”) once, and then the magnetic tape is wound around thecartridge reel (generally, an outer diameter is about 40 to 50 mm) ofthe magnetic tape cartridge from the temporary winding core. Therefore,the magnetic tape can be wound around the cartridge reel of the magnetictape cartridge while maintaining a relationship between an inside and anoutside of the magnetic tape with respect to the winding core for heattreatment during the heat treatment. For details of the temporarywinding core and the tension in winding the magnetic tape around thewinding core, the previous description regarding the winding core forheat treatment can be referred to. In an aspect in which the above heattreatment is performed on a magnetic tape having a length of “finalproduct length+a”, a length of “+a” need only be cut off at any stage.For example, in an aspect, the magnetic tape for the final productlength need only be wound around the reel of the magnetic tape cartridgefrom the temporary winding core, and the remaining length of “+a” needonly be cut off. From the viewpoint of reducing a portion to be cut offand discarded, the a is preferably 20 m or less.

A specific aspect of the heat treatment performed in a state of beingwound around the core-shaped member as described above will be describedbelow.

An atmosphere temperature at which the heat treatment is performed(hereinafter, referred to as a “heat treatment temperature”) ispreferably 40° C. or higher, and more preferably 50° C. or higher. Onthe other hand, from the viewpoint of suppressing excessive deformation,the heat treatment temperature is preferably 75° C. or lower, morepreferably 70° C. or lower, and still more preferably 65° C. or lower.

A weight-basis absolute humidity of an atmosphere in which the heattreatment is performed is preferably 0.1 g/kg Dry air or more, and morepreferably 1 g/kg Dry air or more. An atmosphere having a weight-basisabsolute humidity in the above range is preferable because it can beprepared without using a special device for reducing moisture. On theother hand, the weight-basis absolute humidity is preferably 70 g/kg Dryair or less, and more preferably 66 g/kg Dry air or less, from theviewpoint of suppressing occurrence of dew condensation anddeterioration of workability. A heat treatment time is preferably 0.3hours or more, and more preferably 0.5 hours or more. In addition, theheat treatment time is preferably 48 hours or less from the viewpoint ofproduction efficiency.

Servo Pattern

The term “formation of servo pattern” can also be referred to as“recording of servo signal”. The dimension in the width direction of themagnetic tape can be controlled by acquiring dimension information inthe width direction of the magnetic tape during running by using theservo signal and adjusting and changing the tension applied in thelongitudinal direction of the magnetic tape according to the acquireddimension information.

Hereinafter, the formation of the servo pattern will be described.

The servo pattern is usually formed along the longitudinal direction ofthe magnetic tape. Examples of control (servo control) types using aservo signal include a timing-based servo (TBS), an amplitude servo, anda frequency servo.

As shown in European computer manufacturers association (ECMA)-319 (June2001), a magnetic tape (generally called “LTO tape”) conforming to alinear tape-open (LTO) standard employs a timing-based servo system. Inthis timing-based servo system, the servo pattern is formed bycontinuously disposing a plurality of pairs of non-parallel magneticstripes (also referred to as “servo stripes”) in the longitudinaldirection of the magnetic tape. The servo system is a system thatperforms head tracking using servo signals. In the present invention andthe present specification, the term “timing-based servo pattern” refersto a servo pattern that enables head tracking in a timing-based servosystem. As described above, the reason why the servo pattern is formedof a pair of non-parallel magnetic stripes is to indicate, to a servosignal reading element passing over the servo pattern, a passingposition thereof. Specifically, the pair of magnetic stripes is formedso that an interval thereof continuously changes along a width directionof the magnetic tape, and the servo signal reading element reads theinterval to thereby sense a relative position between the servo patternand the servo signal reading element. Information on this relativeposition enables tracking on a data track. Therefore, a plurality ofservo tracks are usually set on the servo pattern along a widthdirection of the magnetic tape.

A servo band is formed of a servo pattern continuous in the longitudinaldirection of the magnetic tape. A plurality of the servo bands areusually provided on the magnetic tape. For example, in an LTO tape, thenumber of the servo bands is five. Regions interposed between twoadjacent servo bands are data bands. The data band is formed of aplurality of data tracks, and each data track corresponds to each servotrack.

Further, in an aspect, as shown in JP2004-318983A, informationindicating a servo band number (referred to as “servo bandidentification (ID)” or “unique data band identification method (UDIM)information”) is embedded in each servo band. This servo band ID isrecorded by shifting a specific one of the plurality of pairs of theservo stripes in the servo band so that positions thereof are relativelydisplaced in the longitudinal direction of the magnetic tape.Specifically, a way of shifting the specific one of the plurality ofpairs of servo stripes is changed for each servo band. Accordingly, therecorded servo band ID is unique for each servo band, and thus, theservo band can be uniquely specified only by reading one servo band witha servo signal reading element.

As a method for uniquely specifying the servo band, there is a methodusing a staggered method as shown in ECMA-319 (June 2001). In thisstaggered method, a group of pairs of non-parallel magnetic stripes(servo stripes) disposed continuously in plural in the longitudinaldirection of the magnetic tape is recorded so as to be shifted in thelongitudinal direction of the magnetic tape for each servo band. Sincethis combination of shifting methods between adjacent servo bands isunique throughout the magnetic tape, it is possible to uniquely specifya servo band in a case of reading a servo pattern with two servo signalreading elements.

As shown in ECMA-319 (June 2001), information indicating a position ofthe magnetic tape in the longitudinal direction (also referred to as“longitudinal position (LPOS) information”) is usually embedded in eachservo band. This LPOS information is also recorded by shifting thepositions of the pair of servo stripes in the longitudinal direction ofthe magnetic tape, as the UDIM information. Here, unlike the UDIMinformation, in this LPOS information, the same signal is recorded ineach servo band.

It is also possible to embed, in the servo band, the other informationdifferent from the above UDIM information and LPOS information. In thiscase, the embedded information may be different for each servo band asthe UDIM information or may be common to all servo bands as the LPOSinformation.

As a method of embedding information in the servo band, it is possibleto employ a method other than the above. For example, a predeterminedcode may be recorded by thinning out a predetermined pair from the groupof pairs of servo stripes.

A head for forming a servo pattern is called a servo write head. Theservo write head usually has a pair of gaps corresponding to the pair ofmagnetic stripes as many as the number of servo bands. Usually, a coreand a coil are connected to each pair of gaps, and by supplying acurrent pulse to the coil, a magnetic field generated in the core cancause generation of a leakage magnetic field in the pair of gaps. In acase of forming the servo pattern, by inputting a current pulse whilerunning the magnetic tape on the servo write head, the magnetic patterncorresponding to the pair of gaps is transferred to the magnetic tape toform the servo pattern. A width of each gap can be appropriately setaccording to a density of the servo pattern to be formed. The width ofeach gap can be set to, for example, 1 μm or less, 1 to 10 μm, 10 μm ormore, and the like.

Before the servo pattern is formed on the magnetic tape, the magnetictape is usually subjected to a demagnetization (erasing) treatment. Thiserasing treatment can be performed by applying a uniform magnetic fieldto the magnetic tape using a direct current magnet or an alternatingcurrent magnet. The erasing treatment includes direct current (DC)erasing and alternating current (AC) erasing. AC erasing is performed bygradually decreasing an intensity of the magnetic field while reversinga direction of the magnetic field applied to the magnetic tape. On theother hand, DC erasing is performed by applying a unidirectionalmagnetic field to the magnetic tape. As the DC erasing, there are twomethods. A first method is horizontal DC erasing of applying aunidirectional magnetic field along the longitudinal direction of themagnetic tape. A second method is vertical DC erasing of applying aunidirectional magnetic field along the thickness direction of themagnetic tape. The erasing treatment may be performed on the entiremagnetic tape or may be performed for each servo band of the magnetictape.

A direction of the magnetic field of the servo pattern to be formed isdetermined according to a direction of the erasing. For example, in acase where the horizontal DC erasing is performed to the magnetic tape,the servo pattern is formed so that the direction of the magnetic fieldis opposite to the direction of the erasing. Therefore, an output of aservo signal obtained by reading the servo pattern can be increased. Asshown in JP2012-53940A, in a case where a magnetic pattern istransferred to, using the gap, a magnetic tape that has been subjectedto vertical DC erasing, a servo signal obtained by reading the formedservo pattern has a monopolar pulse shape. On the other hand, in a casewhere a magnetic pattern is transferred to, using the gap, a magnetictape that has been subjected to horizontal DC erasing, a servo signalobtained by reading the formed servo pattern has a bipolar pulse shape.

The magnetic tape cartridge may be a magnetic tape cartridge suitablefor a use form in which, after being stored in a high temperature andhigh humidity environment, data is recorded on the magnetic tape and/ordata recorded on the magnetic tape is reproduced in a use environment inwhich the temperature and humidity are significantly lower than those inthe storage environment within a short period of time. A temperature ofthe storage environment may be, for example, about 30° C. to 50° C. Ahumidity of the storage environment may be, for example, about 60% to100% as a relative humidity. In addition, a temperature of the useenvironment may be, for example, about 15° C. to 25° C. A humidity ofthe use environment may be, for example, about 30% to 60% as a relativehumidity. A period of time from the taking out from the storageenvironment to the recording of the data on the magnetic tape and/or thereproduction of data recorded on the magnetic tape in the useenvironment may be, for example, about 30 minutes to 2 hours.

Here, the above-described use form is merely an example, and theabove-described magnetic tape cartridge is not limited to the one usedin such a use form.

Magnetic Tape Apparatus

Another aspect of the present invention relates to a magnetic tapeapparatus including the magnetic tape cartridge.

In the present invention and the present specification, the term“magnetic tape apparatus” means an apparatus capable of performing atleast one of the recording of data on the magnetic tape or thereproduction of data recorded on the magnetic tape. Such an apparatus isgenerally called a drive. In an aspect, the magnetic tape apparatus canbe a sliding type magnetic tape apparatus. The sliding type magnetictape apparatus is an apparatus in which the magnetic layer surface andthe magnetic head come into contact with each other to be slid on eachother, in a case of performing the recording of data on the magnetictape and/or reproduction of recorded data.

The magnetic tape apparatus can include the magnetic tape cartridgeattachably and detachably. Further, the magnetic tape apparatus caninclude a magnetic head. Such a magnetic head can be a recording headcapable of performing the recording of data on the magnetic tape, or canbe a reproducing head capable of performing the reproducing of datarecorded on the magnetic tape. In addition, in an aspect, the magnetictape apparatus can include both of a recording head and a reproducinghead as separate magnetic heads. In another aspect, the magnetic headincluded in the magnetic tape apparatus can have a configuration thatboth of an element for recording data (recording element) and an elementfor reproducing data (reproducing element) are included in one magnetichead. Hereinafter, the element for recording and the element forreproducing data are collectively referred to as an “element for data”.As the reproducing head, a magnetic head (MR head) including amagnetoresistive (MR) element capable of sensitively reading datarecorded on the magnetic tape as a reproducing element is preferable. Asthe MR head, various well-known MR heads such as an anisotropicmagnetoresistive (AMR) head, a giant magnetoresistive (GMR) head, and atunnel magnetoresistive (TMR) head can be used. In addition, themagnetic head which performs the recording of data and/or thereproducing of data may include a servo signal reading element.Alternatively, as a head other than the magnetic head which performs therecording of data and/or the reproducing of data, a magnetic head (servohead) comprising a servo signal reading element may be included in themagnetic tape apparatus. For example, a magnetic head that records dataand/or reproduces recorded data (hereinafter, also referred to as a“recording and reproducing head”) can include two servo signal readingelements, and the two servo signal reading elements can read twoadjacent servo bands simultaneously. One or a plurality of elements fordata can be disposed between the two servo signal reading elements.

In the magnetic tape apparatus, recording of data on the magnetic tapeand/or reproduction of data recorded on the magnetic tape can beperformed as the magnetic layer surface of the magnetic tape and themagnetic head come into contact with each other to be slid on eachother. The above magnetic tape apparatus need only include the magnetictape cartridge according to one embodiment of the present invention, andwell-known technologies can be applied to others.

For example, in a case where data is recorded on the magnetic tape onwhich a servo pattern is formed and/or recorded data is reproduced,first, tracking is performed using a servo signal obtained by readingthe servo pattern. That is, by causing the servo signal reading elementto follow a predetermined servo track, the element for data iscontrolled to pass on the target data track. Displacement of the datatrack is performed by changing a servo track to be read by the servosignal reading element in a tape width direction.

The recording and reproducing head can also perform recording and/orreproduction with respect to other data bands. In this case, the servosignal reading element need only be displaced to a predetermined servoband using the above described UDIM information to start tracking forthe servo band.

In an aspect, the dimension in the width direction of the magnetic tapecan be controlled by acquiring dimension information in the widthdirection of the magnetic tape during running by using the servo signaland adjusting the tension applied in the longitudinal direction of themagnetic tape according to the acquired dimension information. Suchtension adjustment can contribute to preventing the magnetic head forrecording or reproducing data from being deviated from a target trackposition due to width deformation of the magnetic tape during recordingor reproduction.

EXAMPLES

Hereinafter, an aspect of the present invention will be described basedon Examples. Here, the present invention is not limited to aspects shownin Examples. Unless otherwise specified, “parts” and “%” in thefollowing description indicate “parts by mass” and “mass %”. “eq” is anequivalent and is a unit that cannot be converted into an SI unit.

The following various processes and operations were performed in anenvironment of a temperature of 20° C.±25° C. and a relative humidity of40% to 60%, unless otherwise noted.

Non-Magnetic Support

In Table 1, “PEN” indicates a polyethylene naphthalate support, and“PET” indicates a polyethylene terephthalate support.

Ferromagnetic Powder

In Table 1, “BaFe” in the row of the type of a ferromagnetic powderindicates a hexagonal barium ferrite powder having an average particlesize (average plate diameter) of 21 nm.

In Table 1, “SrFe1” in the row of the type of a ferromagnetic powderindicates a hexagonal strontium ferrite powder manufactured by thefollowing method.

1707 g of SrCO₃, 687 g of H₃BO₃, 1120 g of Fe₂O₃, 45 g of Al(OH)₃, 24 gof BaCO₃, 13 g of CaCO₃, and 235 g of Nd₂O₃ were weighed and mixed by amixer to obtain a raw material mixture.

The obtained raw material mixture was melted in a platinum crucible at amelting temperature of 1390° C., and a hot water outlet provided at abottom of the platinum crucible was heated while stirring a melt, andthe melt was discharged in a rod shape at about 6 g/sec. Hot water wasrolled and quenched by a pair of water-cooling rollers to manufacture anamorphous body.

280 g of the manufactured amorphous body was charged into an electricfurnace, was heated to 635° C. (crystallization temperature) at aheating rate of 3.5° C./min, and was held at the same temperature for 5hours to precipitate (crystallize) hexagonal strontium ferriteparticles.

Next, a crystallized product obtained above including hexagonalstrontium ferrite particles was coarsely pulverized in a mortar, and1000 g of zirconia beads having a particle diameter of 1 mm and 800 mLof an acetic acid aqueous solution of 1% concentration were added to thecrystallized product in a glass bottle, to be dispersed by a paintshaker for 3 hours. Thereafter, the obtained dispersion liquid wasseparated from the beads, to be put in a stainless beaker. Thedispersion liquid was statically left at a liquid temperature of 100° C.for 3 hours and subjected to a dissolving treatment of a glasscomponent, and then the crystallized product was sedimented by acentrifugal separator to be washed by repeatedly performing decantationand was dried in a heating furnace at an internal temperature of thefurnace of 110° C. for 6 hours to obtain a hexagonal strontium ferritepowder.

The hexagonal strontium ferrite powder obtained above had an averageparticle size of 18 nm, an activation volume of 902 nm³, an anisotropyconstant Ku of 2.2×10⁵ J/m³, and a mass magnetization σs of 49 A·m²/kg.

12 mg of a sample powder was taken from the hexagonal strontium ferritepowder obtained above, elemental analysis of the filtrated solutionobtained by partially dissolving this sample powder under dissolutionconditions illustrated above was performed by an ICP analyzer, and asurface layer portion content of a neodymium atom was determined.

Separately, 12 mg of a sample powder was taken from the hexagonalstrontium ferrite powder obtained above, elemental analysis of thefiltrated solution obtained by totally dissolving this sample powderunder dissolution conditions illustrated above was performed by an ICPanalyzer, and a bulk content of a neodymium atom was determined.

A content (bulk content) of a neodymium atom with respect to 100 at % ofan iron atom in the hexagonal strontium ferrite powder obtained abovewas 2.9 at %. A surface layer portion content of a neodymium atom was8.0 at %. It was confirmed that a ratio of the surface layer portioncontent to the bulk content, that is, “surface layer portioncontent/bulk content” was 2.8, and the neodymium atoms were unevenlydistributed in the surface layer of particles.

The fact that the powder obtained above shows a crystal structure ofhexagonal ferrite was confirmed by performing scanning with CuKα raysunder conditions of a voltage of 45 kV and an intensity of 40 mA andmeasuring an X-ray diffraction pattern under the following conditions(X-ray diffraction analysis). The powder obtained above showed a crystalstructure of hexagonal ferrite of a magnetoplumbite type (M-type). Acrystal phase detected by X-ray diffraction analysis was a single phaseof a magnetoplumbite type.

PANalytical X'Pert Pro diffractometer, PIXcel detector

Soller slit of incident beam and diffracted beam: 0.017 radians

Fixed angle of dispersion slit: ¼ degrees

Mask: 10 mm

Anti-scattering slit: ¼ degrees

Measurement mode: continuous

Measurement time per stage: 3 seconds

Measurement speed: 0.017 degrees per second

Measurement step: 0.05 degrees

In Table 1, “SrFe2” in the row of the type of a ferromagnetic powderindicates a hexagonal strontium ferrite powder manufactured by thefollowing method.

1725 g of SrCO₃, 666 g of H₃BO₃, 1332 g of Fe₂O₃, 52 g of Al(OH)₃, 34 gof CaCO₃, and 141 g of BaCO₃ were weighed and mixed by a mixer to obtaina raw material mixture.

The obtained raw material mixture was dissolved in a platinum crucibleat a melting temperature of 1380° C., and a hot water outlet provided ata bottom of the platinum crucible was heated while stirring a melt, andthe melt was discharged in a rod shape at about 6 g/sec. Hot water wasrolled and quenched by a pair of water-cooling rollers to manufacture anamorphous body.

280 g of the obtained amorphous body was charged into an electricfurnace, was heated to 645° C. (crystallization temperature), and washeld at the same temperature for 5 hours to precipitate (crystallize)hexagonal strontium ferrite particles.

Next, a crystallized product obtained above including hexagonalstrontium ferrite particles was coarsely pulverized in a mortar, and1000 g of zirconia beads having a particle diameter of 1 mm and 800 mLof an acetic acid aqueous solution of 1% concentration were added to thecrystallized product in a glass bottle, to be dispersed by a paintshaker for 3 hours. Thereafter, the obtained dispersion liquid wasseparated from the beads, to be put in a stainless beaker. Thedispersion liquid was statically left at a liquid temperature of 100° C.for 3 hours and subjected to a dissolving treatment of a glasscomponent, and then the crystallized product was sedimented by acentrifugal separator to be washed by repeatedly performing decantationand was dried in a heating furnace at an internal temperature of thefurnace of 110° C. for 6 hours to obtain a hexagonal strontium ferritepowder.

The obtained hexagonal strontium ferrite powder had an average particlesize of 19 nm, an activation volume of 1102 nm³, an anisotropy constantKu of 2.0×10⁵ J/m³, and a mass magnetization σs of 50 A·m²/kg.

In Table 1, “ε-Iron oxide” in the row of the type of a ferromagneticpowder indicates an ε-iron oxide powder manufactured by the followingmethod.

8.3 g of iron(III) nitrate nonahydrate, 1.3 g of gallium(III) nitrateoctahydrate, 190 mg of cobalt(II) nitrate hexahydrate, 150 mg oftitanium(IV) sulfate, and 1.5 g of polyvinylpyrrolidone (PVP) weredissolved in 90 g of pure water, and while the dissolved product wasstirred using a magnetic stirrer, 4.0 g of an aqueous ammonia solutionhaving a concentration of 25% was added to the dissolved product under acondition of an atmosphere temperature of 25° C. in an air atmosphere,and the dissolved product was stirred for 2 hours while maintaining atemperature condition of the atmosphere temperature of 25° C. A citricacid aqueous solution obtained by dissolving 1 g of citric acid in 9 gof pure water was added to the obtained solution, and the mixture wasstirred for 1 hour. The powder sedimented after stirring was collectedby centrifugal separation, was washed with pure water, and was dried ina heating furnace at a furnace temperature of 80° C.

800 g of pure water was added to the dried powder, and the powder wasdispersed again in water to obtain dispersion liquid. The obtaineddispersion liquid was heated to a liquid temperature of 50° C., and 40 gof an aqueous ammonia solution having a concentration of 25% wasdropwise added with stirring. After stirring for 1 hour whilemaintaining the temperature at 50° C., 14 mL of tetraethoxysilane (TEOS)was dropwise added and was stirred for 24 hours. A powder sedimented byadding 50 g of ammonium sulfate to the obtained reaction solution wascollected by centrifugal separation, was washed with pure water, and wasdried in a heating furnace at a furnace temperature of 80° C. for 24hours to obtain a ferromagnetic powder precursor.

The obtained ferromagnetic powder precursor was mounted on a heatingfurnace at a furnace temperature of 1000° C. in an air atmosphere andwas heat-treated for 4 hours.

The heat-treated ferromagnetic powder precursor was put into an aqueoussolution of 4 mol/L sodium hydroxide (NaOH), and the liquid temperaturewas maintained at 70° C. and was stirred for 24 hours, whereby a silicicacid compound as an impurity was removed from the heat-treatedferromagnetic powder precursor.

Thereafter, the ferromagnetic powder from which the silicic acidcompound was removed was collected by centrifugal separation, and waswashed with pure water to obtain a ferromagnetic powder.

The composition of the obtained ferromagnetic powder that was confirmedby high-frequency inductively coupled plasma-optical emissionspectrometry (ICP-OES) has Ga, Co, and a Ti substitution type ε-ironoxide (ε-Ga_(0.28)Co_(0.05)Ti_(0.05)Fe_(1.62)O₃). In addition, X-raydiffraction analysis was performed under the same condition as describedabove for the hexagonal strontium ferrite powder SrFe1, and from a peakof an X-ray diffraction pattern, it was confirmed that the obtainedferromagnetic powder does not include α-phase and γ-phase crystalstructures, and has a single-phase and ε-phase crystal structure (ε-ironoxide type crystal structure).

The obtained ε-iron oxide powder had an average particle size of 12 nm,an activation volume of 746 nm³, an anisotropy constant Ku of 1.2×10⁵J/m³, and a mass magnetization as of 16 A·m²/kg.

An activation volume and an anisotropy constant Ku of the abovehexagonal strontium ferrite powder and ε-iron oxide powder are valuesobtained by the method described above using a vibrating samplemagnetometer (manufactured by Toei Industry Co., Ltd.) for eachferromagnetic powder.

A mass magnetization as is a value measured at a magnetic fieldintensity of 1194 kA/m (15 kOe) using a vibrating sample magnetometer(manufactured by Toei Industry Co., Ltd.).

Example 1

Manufacturing of Magnetic Tape Cartridge

(1) Preparation of Alumina Dispersion

3.0 parts of 2,3-dihydroxynaphthalene (manufactured by Tokyo ChemicalIndustry Co., Ltd.), 31.3 parts of a 32% solution (solvent is a mixedsolvent of methyl ethyl ketone and toluene) of a polyester polyurethaneresin having a SO₃Na group as a polar group (UR-4800 manufactured byToyobo Co., Ltd. (amount of a polar group: 80 meq/kg)), and 570.0 partsof a mixed solution of methyl ethyl ketone and cyclohexanone at 1:1(mass ratio) as a solvent were mixed with respect to 100.0 parts of analumina powder (HIT-80 manufactured by Sumitomo Chemical Co., Ltd.)having a pregelatinization ratio of about 65% and aBrunauer-Emmett-Teller (BET) specific surface area of 20 m²/g, anddispersed in the presence of zirconia beads by a paint shaker for 5hours. After the dispersion, the dispersion liquid and the beads wereseparated by a mesh to obtain an alumina dispersion.

(2) Formulation of Magnetic Layer Forming Composition

Magnetic Liquid Ferromagnetic powder (see Table 1) 100.0 parts SO₃Nagroup-containing polyurethane resin 14.0 parts weight-average molecularweight: 70,000, SO₃Na group: 0.2 meq/g Cyclohexanone: 150.0 parts Methylethyl ketone: 150.0 parts Abrasive Liquid Alumina dispersion prepared in(1) above 6.0 parts Silica Sol (Protrusion Forming Agent Liquid)Colloidal silica (average particle size: 120 nm) 2.0 parts Methyl ethylketone 1.4 parts Other Components Stearic acid 2.0 parts Stearic acidamide 0.2 parts Butyl stearate 2.0 parts Polyisocyanate (CORONATE(registered trademark) 2.5 parts L manufactured by Tosoh Corporation)Finishing Additive Solvent Cyclohexanone 200.0 parts Methyl ethyl ketone200.0 parts

(3) Formulation of Non-Magnetic Layer Forming Composition

Non-magnetic inorganic powder: α-iron oxide: 100.0 parts Averageparticle size (average long axis length): 0.15 μm Average acicularratio: 7 BET specific surface area: 52 m²/g 20.0 parts Carbon blackAverage particle size: 20 nm 18.0 parts SO₃Na group-containingpolyurethane resin weight-average molecular weight: 70,000, 0.2 meq/gSO₃Na group: Stearic acid 2.0 parts Stearic acid amide 0.2 parts Butylstearate 2.0 parts Cyclohexanone 300.0 parts Methyl ethyl ketone 300.0parts

(4) Formulation of Back Coating Layer Forming Composition

Carbon black 100.0 parts Dibutyl phthalate (DBP) oil absorption 74cm³/100 g Nitrocellulose 27.0 parts Polyester polyurethane resincontaining sulfonic 62.0 parts acid group and/or salt thereof Polyesterresin 4.0 parts Alumina powder (BET specific surface area: 0.6 parts 17m²/g) Methyl ethyl ketone 600.0 parts Toluene 600.0 parts Polyisocyanate(CORONATE L manufactured 15.0 parts by Tosoh Corporation)

(5) Preparation of Each Layer Forming Composition

A magnetic layer forming composition was prepared by the followingmethod.

Various components of the magnetic liquid were dispersed (beaddispersion) for 24 hours using a batch type vertical sand mill toprepare a magnetic liquid. As dispersed beads, zirconia beads having abead diameter of 0.5 mm were used. Using the sand mill, the preparedmagnetic liquid, the abrasive liquid, and other components (silica sol,other components, and finishing additive solvent) were mixed andbead-dispersed for 5 minutes, and then subjected to a treatment(ultrasonic dispersion) for 0.5 minutes by a batch type ultrasonicdevice (20 kHz, 300 W). Thereafter, filtration was performed using afilter having a pore diameter of 0.5 μm to prepare a magnetic layerforming composition.

A non-magnetic layer forming composition was prepared by the followingmethod. The components excluding a lubricant (stearic acid, stearic acidamide, and butyl stearate) were kneaded and diluted by an open kneader,and then subjected to a dispersion treatment by a horizontal beads milldispersing device. After that, the lubricant (stearic acid, stearic acidamide, and butyl stearate) was added into the obtained dispersion liquidand stirred and mixed by a dissolver stirrer to prepare a non-magneticlayer forming composition.

A back coating layer forming composition was prepared by the followingmethod. The above components excluding polyisocyanate were introducedinto a dissolver stirrer, stirred at a circumferential speed of 10 msecfor 30 minutes, and then subjected to a dispersion treatment by ahorizontal beads mill dispersing device. After that, polyisocyanate wasadded into the obtained dispersion liquid and stirred and mixed by adissolver stirrer to prepare a back coating layer forming composition.

(6) Method of Manufacturing of Magnetic Tape and Magnetic Tape Cartridge

The non-magnetic layer forming composition prepared in (5) above wasapplied onto a surface of a biaxially stretched support of the type andthickness shown in Table 1 and was dried so that the thickness afterdrying is a value shown in Table 1, and thus a non-magnetic layer wasformed. Next, the magnetic layer forming composition prepared in (5)above was applied onto the non-magnetic layer so that the thicknessafter drying is a value shown in Table 1, and thus a coating layer wasformed. After that, while this coating layer of the magnetic layerforming composition is in a wet state, a vertical orientation treatmentwas performed by applying a magnetic field of a magnetic field intensityof 0.3 T in a direction perpendicular to a surface of the coating layer,and then the surface of the coating layer was dried. Thereby, a magneticlayer was formed. After that, the back coating layer forming compositionprepared in (5) above was applied onto a surface of the support oppositeto the surface on which the non-magnetic layer and the magnetic layerare formed and was dried so that the thickness after drying is athickness shown in Table 1, and thus, a back coating layer was formed.

After that, a surface smoothing treatment (calendering treatment) wasperformed using a calendar roll formed of only metal rolls at a speed of100 m/min, a linear pressure of 300 kg/cm, and a calendar temperature of90° C. (surface temperature of calendar roll).

After that, a long magnetic tape original roll was stored in a heattreatment furnace having an atmosphere temperature of 70° C. to performa heat treatment (heat treatment time: 36 hours). After the heattreatment, the magnetic tape original roll was slit to obtain a magnetictape having ½ inches width. The slitting was performed in a slittingdevice having a configuration shown in FIG. 4 of JP2002-269711A. A cycleof a sucking section of the slitting device was 13.5 mm, and a porousmetal was embedded in the sucking section to form a mesh suction. Adriving belt and a coupling material of a power transmission device thattransmits power to a blade drive unit of the slitting device were usedas shown in Table 1, and slitting was performed using a suckingpressure, a winding angle of a magnetic tape original roll with respectto a tension cut roller, and a slitting speed as values shown in Table1.

After the slitting, a servo signal was recorded on the magnetic layer ofthe obtained magnetic tape by a commercially available servo writer toobtain a magnetic tape having a data band, a servo band, and a guideband in an arrangement according to a linear tape-open (LTO) Ultriumformat and having a servo pattern (timing-based servo pattern) in anarrangement and a shape according to the LTO Ultrium format on the servoband. The servo pattern thus formed is a servo pattern according to thedescription in Japanese industrial standards (JIS) X6175:2006 andStandard ECMA-319 (June 2001).

The magnetic tape (length of 960 m) after recording the servo signal waswound around a winding core for heat treatment, and was heat-treated ina state of being wound around the core. As the winding core for heattreatment, a resin-made solid core-shaped member (outer diameter: 50 mm)having a flexural modulus of 0.8 GPa was used, and the tension duringwinding was 0.60 N. The heat treatment was performed at a heat treatmenttemperature of 55° C. for 5 hours. A weight-basis absolute humidity ofthe heat-treated atmosphere was 10 g/kg Dry air.

After the above heat treatment, the magnetic tape and the winding corefor heat treatment were sufficiently cooled, and then the magnetic tapewas removed from the winding core for heat treatment and wound aroundthe temporary winding core. After that, the magnetic tape of the finalproduct length (950 m) was wound (winding tension: see Table 1) aroundthe reel (reel outer diameter: 44 mm) of the magnetic tape cartridge(LTO Ultrium 7 data cartridge) from the temporary winding core, theremaining 10 m was cut off, and a leader tape (length of 1 m) accordingto item 9 of Section 3 of European computer manufacturers association(ECMA)-319 (June 2001) was joined to the end of the cutting side by acommercially available splicing tape. As the temporary winding core, asolid core-shaped member made of the same material and having the sameouter diameter as the winding core for heat treatment was used, and thetension during winding was 0.60 N.

As described above, a single reel type magnetic tape cartridge ofExample 1 in which a magnetic tape having a total length of 951 mincluding a leader tape was wound around a reel was manufactured.

By repeating the above processes, a plurality of magnetic tapecartridges were manufactured and used for the following (7) to (10),respectively.

(7) Measurement of Water Absorption Amount

A water absorption amount for the magnetic tape cartridge, which wasmeasured in terms of the length of the magnetic tape of 1000 m, afterthe magnetic tape cartridge was stored in a storage environment of atemperature of 32° C. and a relative humidity of 80% for 10 days wasobtained by the method described above. The mass of the magnetic tapecartridge was measured using a UX2200H manufactured by ShimadzuCorporation.

(8) Edge Weave Amount α and Cycle f

An edge weave amount measuring device (manufactured by KeyenceCorporation) was attached to a commercially available servo writer, andthe edge weave amount was continuously measured over a tape length of 50m at the tape edge on one side serving as the running reference side.Fourier analysis of the obtained edge weave amount α was performed toobtain the cycle f of the edge weave.

(9) Tape Thickness

10 tape samples (length of 5 cm) were cut out from any part of themagnetic tape taken out from each magnetic tape cartridge, and thethickness was measured by stacking these tape samples. The thickness wasmeasured using a digital thickness gauge of Millimar 1240 compactamplifier and Millimar 1301 induction probe manufactured by Mahr Inc. Avalue (thickness per tape sample) obtained by dividing the measuredthickness by 1/10 was defined as the tape thickness.

(10) Friction Coefficient

In order to evaluate the friction characteristics in a state of beingexposed to environmental change from a high temperature and highhumidity environment to an environment with lower temperature andhumidity within a short period of time, the friction coefficient wasobtained by the following method.

The magnetic tape cartridge was placed in a measurement environment witha temperature of 21° C. and a relative humidity of 50% for 5 days ormore and allowed to acclimatize to the measurement environment.

The magnetic tape cartridge was stored in a storage environment with atemperature of 32° C. and a relative humidity of 80% for 10 days.

Within 1 hour after the above storage, the friction coefficient withrespect to the magnetic head was obtained by the following method in ameasurement environment with a temperature of 21° C. and a relativehumidity of 50%. As the magnetic head, a linear tape-open (LTO) 8 headmanufactured by IBM Corporation was used.

The magnetic tape taken out from the magnetic tape cartridge was placedon two cylindrical guide rolls having a diameter of 1 inch (1 inch=2.54cm) spaced apart from each other and arranged in parallel with eachother such that the magnetic layer surface thereof was in contact withthe guide rolls. In a randomly extracted portion of the magnetic tape tobe measured, the magnetic layer surface of the magnetic tape was slidwith respect to the LTO8 head, and a resistance force generated duringthe sliding was detected by a strain gauge. Reciprocating sliding wasperformed 100 times. Regarding measurement conditions, a lap angle θ was6° and a sliding speed was 30 mm/sec. The tension applied in thelongitudinal direction of the magnetic tape during the sliding was setto 1.50 N. A sliding distance for each of a forward path and a returnpath was set to 5 cm. A friction coefficient (dynamic frictioncoefficient) in the 100th forward path was obtained. In a case of theabove measurement, one end of both ends of the magnetic tape to bemeasured in the longitudinal direction was connected to the straingauge, and a tension of 1.50 N was applied to the other end. Assumingthat the tension applied here was T₀ (unit: N) and the resistance forcedetected by the strain gauge is T (unit: N), the friction coefficient μvalue was calculated by the following equation. That is, the frictioncoefficient μ value was calculated with T₀=1.50.

$\mu = {\frac{1}{\theta \times \left( {\pi\text{/}180} \right)} \times \log_{e}\frac{T}{T_{0}}}$

Examples 2 to 36 and Comparative Examples 1 to 15

A magnetic tape cartridge was manufactured and various evaluations wereperformed in the same manner as in Example 1 except that the items inTable 1 were changed as shown in Table 1.

In Examples in which “Performed” is described in the row of “Directdrive” in Table 1, the blade drive unit was directly driven by a motorto perform slitting without using a power transmission device using abelt. In addition, in Comparative Examples in which “No mesh” isdescribed in the row of “Sucking section”, slitting was performedwithout embedding the porous metal in the sucking section of theslitting device.

The above results are shown in Table 1 (Tables 1-1 to 1-6).

TABLE 1-1 Example Example Example Example Example Example ExampleExample Example 1 2 3 4 5 6 7 8 9 Type of ferromagnetic BaFe BaFe BaFeBaFe BaFe BaFe BaFe BaFe BaFe powder Thickness of 0.1 μm 0.1 μm 0.1 μm0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm magnetic layer Thickness ofnon- 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0 μmmagnetic layer Thickness of non- 4.0 μm 4.0 μm 4.0 μm 4.0 μm 4.0 μm 4.0μm 4.0 μm 4.0 μm 4.0 μm magnetic support Thickness of back 0.5 μm 0.5 μm0.5 μm 0.5 μm 0.5 μm 0.5 μm 0.5 μm 0.5 μm 0.5 μm coating layer Tapethickness 5.6 μm 5.6 μm 5.6 μm 5.6 μm 5.6 μm 5.6 μm 5.6 μm 5.6 μm 5.6 μmType of non- PET PET PET PET PET PET PET PET PET magnetic supportYoung's modulus of 4000 4000 4000 4000 4000 4000 4000 4000 3500non-magnetic support Width direction (MPa) Young's modulus of 7000 70007000 7000 7000 7000 7000 7000 7000 non-magnetic support Longitudinaldirection direction (MPa) Moisture content of 0.50% 0.50% 0.50S 0.50%0.50% 0.50% 0.50% 0.50% 0.50% non-magnetic support Sucking section MeshMesh Mesh Mesh Mesh Mesh Mesh Mesh Mesh Sucking pressure 13.3 13.3 13.313.3 13.3 13.3 13.3 13.3 13.3 (×1000 Pa) Winding angle 188 188 188 188188 188 188 188 188 degrees degrees degrees degrees degrees degreesdegrees degrees degrees Driving belt Flat belt Flat belt — Flat beltFlat belt Flat belt — — Flat belt Coupling material RubberVibrationproof — Rubber Vibrationproof Vibrationproof — — Rubber rubberrubber rubber Direct drive — — Performed — — — Performed Performed —Slitting speed (m/min) 200 200 200 300 300 400 300 400 200 Cycle f 65.0mm 65.0 mm 65.0 mm 98.0 mm 98.0 mm 130.0 mm 98.0 mm 130.0 mm 65.0 mmEdge weave amount α 1.5 μm 1.3 μm 0.8 μm 1.5 μm 1.3 μm 1.3 μm 0.8 μm 0.8μm 1.5 μm Winding tension 1.00N 1.00N 1.00N 1.00N 1.00N 1.00N 1.00N1.00N 1.00N Water absorption 0.30 g 0.30 g 0.30 g 0.30 g 0.30 g 0.30 g0.30 g 0.30 g 0.30 g amount Friction coefficient 0.5 0.5 0.5 0.5 0.5 0.50.5 0.5 0.5

TABLE 1-2 Example Example Example Example Example Example ExampleExample Example 10 11 12 13 14 15 16 17 18 Type of ferromagnetic powderBaFe BaFe BaFe BaFe BaFe BaFe SrFe1 SrFe2 ε-Iron oxide Thickness ofmagnetic layer 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm0.1 μm Thickness of non-magnetic layer 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0μm 0.9 μm 0.9 μm 0.9 μm 0.9 μm Thickness of non-magnetic support 4.0 μm4.0 μm 4.0 μm 4.0 μm 4.0 μm 3.8 μm 3.8 μm 3.8 μm 3.8 μm Thickness ofback coating layer 0.5 μm 0.5 μm 0.5 μm 0.5 μm 0.2 μm 0.2 μm 0.2 μm 0.2μm 0.2 μm Tape thickness 5.6 μm 5.6 μm 5.6 μm 5.6 μm 5.3 μm 5.0 μm 5.0μm 5.0 μm 5.0 μm Type of non-magnetic support PET PET PET PET PET PETPET PET PET Young's modulus of non-magnetic 4000 4000 4000 4000 40004000 4000 4000 4000 support Width direction (MPa) Young's modulus ofnon-magnetic 7000 7000 7000 7000 7000 7000 7000 7000 7000 supportLongitudinal direction direction (MPa) Moisture content of non-magnetic0.20% 0.50% 0.50% 0.20% 0.20% 0.20% 0.20% 0.20% 0.20% support Suckingsection Mesh Mesh Mesh Mesh Mesh Mesh Mesh Mesh Mesh Sucking pressure(×1000 Pa) 13.3 13.3 13.3 13.3 13.3 13.3 13.3 13.3 13.3 Winding angle188 188 188 188 188 188 188 188 188 degrees degrees degrees degreesdegrees degrees degrees degrees degrees Driving belt Flat belt Flat beltFlat belt Flat belt Flat belt Flat belt Flat belt Flat belt Flat beltCoupling material Rubber Rubber Rubber Rubber Rubber Rubber RubberRubber Rubber Direct drive — — — — — — — — — Slitting speed (m/min) 200200 200 200 200 200 200 200 200 Cycle f 65.0 mm 65.0 mm 65.0 mm 65.0 mm65.0 mm 65.0 mm 65.0 mm 65.0 mm 65.0 mm Edge weave amount α 1.5 μm 1.5μm 1.5 μm 1.5 μm 1.5 μm 1.5 μm 1.5 μm 1.5 μm 1.5 μm Winding tension1.00N 1.50N 0.80N 1.50N 1.50N 1.50N 1.50N 1.50N 1.50N Water absorptionamount 0.30 g 0.10 g 0.30 g 0.10 g 0.10 g 0.10 g 0.10 g 0.10 g 0.10 gFriction coefficient 0.4 0.3 0.6 0.3 0.3 0.3 0.3 0.3 0.3

TABLE 1-3 Example Example Example Example Example Example ExampleExample Example 19 20 21 22 23 24 25 26 27 Type of ferromagnetic BaFeBaFe BaFe BaFe BaFe BaFe BaFe BaFe BaFe powder Thickness of magnetic 0.1μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm layerThickness of non- 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0μm 1.0 μm magnetic layer Thickness of non- 4.0 μm 4.0 μm 4.0 μm 4.0 μm4.0 μm 4.0 μm 4.0 μm 4.0 μm 4.0 μm magnetic support Thickness of back0.5 μm 0.5 μm 0.5 μm 0.5 μm 0.5 μm 0.5 μm 0.5 μm 0.5 μm 0.5 μm coatinglayer Tape thickness 5.6 μm 5.6 μm 5,6 μm 5.6 μm 5.6 μm 5.6 μm 5.6 μm5.6 μm 5.6 μm Type of non-magnetic PEN PEN PEN PEN PEN PEN PEN PEN PENsupport Young's modulus of 4000 4000 4000 4000 4000 4000 4000 4000 4000non-magnetic support Width direction (MPa) Young's modulus of 8000 80008000 8000 8000 8000 8000 8000 7000 non-magnetic support Longitudinaldirection direction (MPa) Moisture content of 0.60% 0.60% 0.60% 0.60%0.60% 0.60% 0.60% 0.60% 0.50% non-magnetic support Sucking section MeshMesh Mesh Mesh Mesh Mesh Mesh Mesh Mesh Sucking pressure 13.3 13.3 13.313.3 13.3 13.3 13.3 13.3 13.3 (×1000 Pa) Winding angle 188 188 188 188188 188 188 188 188 degrees degrees degrees degrees degrees degreesdegrees degrees degrees Driving belt Flat belt Flat belt — Flat beltFlat belt Flat belt — — Flat belt Coupling material RubberVibrationproof — Rubber Vibrationproof Vibrationproof — — Rubber rubberrubber rubber Direct drive — — Performed — — — Performed Performed —Slitting speed (m/min) 200 200 200 300 300 400 300 400 200 Cycle f 65.0mm 65.0 mm 65.0 mm 98.0 mm 98.0 mm 130.0 mm 98.0 mm 130.0 mm 65.0 mmEdge weave amount α 1.5 μm 1.3 μm 0.8 μm 1.5 μm 1.3 μm 1.3 μm 0.8 μm 0.8μm 1.5 μm Winding tension 1.00N 1.00N 1.00N 1.00N 1.00N 1.00N 1.00N1.00N 1.00N Water absorption 0.30 g 0.30 g 0.30 g 0.30 g 0.30 g 0.30 g0.30 g 0.30 g 0.30 g amount Friction coefficient 0.5 0.5 0.5 0.5 0.5 0.50.5 0.5 0.5

TABLE 1-4 Example Example Example Example Example Example ExampleExample Example 28 29 30 31 32 33 34 35 36 Type of ferromagnetic powderBaFe BaFe BaFe BaFe BaFe BaFe SrFe1 SrFe2 ε-Iron oxide Thickness ofmagnetic layer 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm0.1 μm Thickness of non-magnetic layer 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0μm 0.9 μm 0.9 μm 0.9 μm 0.9 μm Thickness of non-magnetic support 4.0 μm4.0 μm 4.0 μm 4.0 μm 4.0 μm 3.8 μm 3.8 μm 3.8 μm 3.8 μm Thickness ofback coating layer 0.5 μm 0.5 μm 0.5 μm 0.5 μm 0.2 μm 0.2 μm 0.2 μm 0.2μm 0.2 μm Tape thickness 5.6 μm 5.6 μm 5.6 μm 5.6 μm 5.3 μm 5.0 μm 5.0μm 5.0 μm 5.0 μm Type of non-magnetic support PEN PEN PEN PEN PEN PENPEN PEN PEN Young's modulus of non-magnetic 4000 4000 4000 4000 40004000 4000 4000 4000 support Width direction (MPa) Young's modulus ofnon-magnetic 7000 8000 8000 7000 7000 7000 7000 7000 7000 supportLongitudinal direction direction (MPa) Moisture content of non-magnetic0.20% 0.60% 0.60% 0.20% 0.20% 0.20% 0.20% 0.20% 0.20% support Suckingsection Mesh Mesh Mesh Mesh Mesh Mesh Mesh Mesh Mesh Sucking pressure(×1000 Pa) 13.3 13.3 13.3 13.3 13.3 13.3 13.3 13.3 13.3 Winding angle188 188 188 188 188 188 188 188 188 degrees degrees degrees degreesdegrees degrees degrees degrees degrees Driving belt Flat belt Flat beltFlat belt Flat belt Flat belt Flat belt Flat belt Flat belt Flat beltCoupling material Rubber Rubber Rubber Rubber Rubber Rubber RubberRubber Rubber Direct drive — — — — — — — — — Slitting speed (m/min) 200200 200 200 200 200 200 200 200 Cycle f 65.0 mm 65.0 mm 65.0 mm 65.0 mm65.0 mm 65.0 mm 65.0 mm 65.0 mm 65.0 mm Edge weave amount α 1.5 μm 1.5μm 1.5 μm 1.5 μm 1.5 μm 1.5 μm 1.5 μm 1.5 μm 1.5 μm Winding tension1.00N 1.50N 0.80N 1.50N 1.50N 1.50N 1.50N 1.50N 1.50N Water absorptionamount 0.30 g 0.10 g 0.30 g 0.10 g 0.10 g 0.10 g 0.10 g 0.10 g 0.10 gFriction coefficient 0.4 0.3 0.6 0.3 0.3 0.3 0.3 0.3 0.3

TABLE 1-5 Compar- Compar- Compar- Compar- Compar- Compar- Compar-Compar- Compar- ative ative ative ative ative ative ative ative ativeExample Example Example Example Example Example Example Example Example1 2 3 4 5 6 7 8 9 Type of ferromagnetic powder BaFe BaFe BaFe BaFe BaFeBaFe BaFe BaFe BaFe Thickness of magnetic layer 0.1 μm 0.1 μm 0.1 μm 0.1μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm Thickness of non-magnetic layer1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0 μm Thicknessof non-magnetic support 4.0 μm 4.0 μm 4.0 μm 4.0 μm 4.0 μm 4.0 μm 4.0 μm4.0 μm 4.0 μm Thickness of back coating layer 0.5 μm 0.5 μm 0.5 μm 0.5μm 0.5 μm 0.5 μm 0.5 μm 0.5 μm 0.2 μm Tape thickness 5.6 μm 5.6 μm 5.6μm 5.6 μm 5.6 μm 5.6 μm 5.6 μm 5.6 μm 5.3 μm Type of non-magneticsupport PET PET PET PET PET PET PET PET PET Young's modulus ofnon-magnetic 7000 6800 5000 7000 7000 7000 7000 7000 7000 support Widthdirection (MPa) Young's modulus of non-magnetic 4000 4000 6000 4000 40004000 4000 4000 4000 support Longitudinal direction direction (MPa)Moisture content of non-magnetic 2.00% 2.00% 2.00% 1.00% 2.00% 2.00%2.00% 2.00% 2.00% support Sucking section No mesh No mesh No mesh Nomesh No mesh Mesh No mesh No mesh No mesh Sucking pressure (×1000 Pa)1.33 1.33 1.33 1.33 1.33 13.3 1.33 1.33 1.33 Winding angle 188 188 188188 188 188 188 188 188 degrees degrees degrees degrees degrees degreesdegrees degrees degrees Driving belt Flat belt Flat belt Flat belt Flatbelt Timing belt Flat belt Flat belt Flat belt Flat belt Couplingmaterial Rubber Rubber Rubber Rubber Metal Rubber Rubber Rubber RubberDirect drive — — — — — — — — — Slitting speed (m/min) 200 200 200 200200 200 200 200 200 Cycle f 13.5 mm 13.5 mm 13.5 mm 13.5 mm 13.5 mm 65mm 13.5 mm 13.5 mm 13.5 mm Edge weave amount α 2.5 μm 2.5 μm 2.5 μm 2.5μm 3.0 μm 1.5 μm 2.5 μm 2.5 μm 2.5 μm Winding tension 0.40N 0.40N 0.40N0.40N 0.40N 0.40N 0.25N 0.10N 0.40N Water absorption amount 0.40 g 0.40g 0.40 g 0.40 g 0.40 g 0.40 g 0.50 g 0.60 g 0.40 g Friction coefficient1.0 1.0 1.0 1.0 1.0 1.0 1.2 1.3 1.0

TABLE 1-6 Comparative Comparative Comparative Comparative ComparativeComparative Example 10 Example 11 Example 12 Example 13 Example 14Example 15 Type of ferromagnetic powder BaFe BaFe BaFe BaFe BaFe BaFeThickness of magnetic layer 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μm 0.1 μmThickness of non-magnetic layer 0.9 μm 1.0 μm 1.0 μm 1.0 μm 1.0 μm 1.0μm Thickness of non-magnetic support 3.8 μm 4.0 μm 4.0 μm 4.0 μm 4.0 μm4.0 μm Thickness of back coating layer 0.2 μm 0.5 μm 0.5 μm 0.5 μm 0.5μm 0.5 μm Tape thickness 5.0 μm 5.6 μm 5.6 μm 5.6 μm 5.6 μm 5.6 μm Typeof non-magnetic support PET PET PET PET PEN PEN Young's modulus ofnon-magnetic support 7000 7000 7000 4000 8000 8000 Width direction (MPa)Young's modulus of non-magnetic support 4000 4000 4000 7000 4000 4000Longitudinal direction direction (MPa) Moisture content of non-magneticsupport 2.00% 2.00% 2.00% 0.50% 2.00% 1.00% Sucking section No mesh Nomesh Mesh No mesh No mesh No mesh Sucking pressure (×1000 Pa) 1.33 1.3313.3 1.33 1.33 1.33 Winding angle 188 degrees 188 degrees 188 degrees188 degrees 188 degrees 188 degrees Driving belt Flat belt Flat beltFlat belt Flat belt Flat belt Flat belt Coupling material Rubber RubberRubber Rubber Rubber Rubber Direct drive — — — — — — Slitting speed(m/min) 200 200 200 200 200 200 Cycle f 13.5 mm 13.5 mm 65.0 mm 13.5 mm13.5 mm 13.5 mm Edge weave amount α 2.5 μm 2.5 μm 1.5 μm 2.5 μm 2.5 μm2.5 μm Winding tension 0.40N 1.00N 0.40N 0.40N 0.40N 0.40N Waterabsorption amount 0.40 g 0.40 g 0.40 g 0.40 g 0.40 g 0.40 g Frictioncoefficient 1.0 0.9 1.0 0.9 1.0 1.0

As shown in Table 1, the friction coefficient obtained in Examples wassmaller than the friction coefficient obtained in Comparative Examples.From the result, it can be confirmed that the magnetic tape cartridge ofExamples is a magnetic tape cartridge comprising a magnetic tape havingexcellent friction characteristics in a state of being exposed toenvironmental change from a high temperature and high humidityenvironment to an environment with lower temperature and humidity withina short period of time.

One embodiment of the present invention is effective in data storageapplications.

What is claimed is:
 1. A magnetic tape cartridge comprising: a magnetictape that is accommodated in the magnetic tape cartridge while beingwound around a reel hub, wherein a water absorption amount of themagnetic tape measured after the magnetic tape cartridge is stored in astorage environment with a temperature of 32° C. and a relative humidityof 80% for 10 days is more than 0 g and 0.30 g or less as a value interms of a length of the magnetic tape of 1000 m, the water absorptionamount is a value measured in a measurement environment with atemperature of 21° C. and a relative humidity of 50% within 1 hour afterthe storage, the magnetic tape comprises a non-magnetic support having amoisture content of 0% or more and 0.80% or less; and the edge weaveamount of the tape edge on at least one side of the magnetic tape is 0.1μm or more and 1.5 μm or less.
 2. The magnetic tape cartridge accordingto claim 1, wherein the water absorption amount is 0.10 g or more and0.30 g or less.
 3. The magnetic tape cartridge according to claim 1,wherein the magnetic tape has a non-magnetic support and a magneticlayer including a ferromagnetic powder, and the non-magnetic support isa polyester support.
 4. The magnetic tape cartridge according to claim3, wherein the magnetic tape further has a non-magnetic layer includinga non-magnetic powder between the non-magnetic support and the magneticlayer.
 5. The magnetic tape cartridge according to claim 3, wherein themagnetic tape further has a back coating layer including a non-magneticpowder on a surface side of the non-magnetic support opposite to asurface side having the magnetic layer.
 6. The magnetic tape cartridgeaccording to claim 1, wherein a tape thickness of the magnetic tape is5.6 μm or less.
 7. The magnetic tape cartridge according to claim 1,wherein a tape thickness of the magnetic tape is 5.3 μm or less.
 8. Amagnetic tape apparatus comprising: the magnetic tape cartridgeaccording to claim
 1. 9. The magnetic tape apparatus according to claim8, wherein the water absorption amount is 0.10 g or more and 0.30 g orless.
 10. The magnetic tape apparatus according to claim 8, wherein themagnetic tape has a non-magnetic support and a magnetic layer includinga ferromagnetic powder, and the non-magnetic support is a polyestersupport.
 11. The magnetic tape apparatus according to claim 10, whereinthe magnetic tape further has a non-magnetic layer including anon-magnetic powder between the non-magnetic support and the magneticlayer.
 12. The magnetic tape apparatus according to claim 10, whereinthe magnetic tape further has a back coating layer including anon-magnetic powder on a surface side of the non-magnetic supportopposite to a surface side having the magnetic layer.
 13. The magnetictape apparatus according to claim 8, wherein a tape thickness of themagnetic tape is 5.6 μm or less.
 14. The magnetic tape apparatusaccording to claim 8, wherein a tape thickness of the magnetic tape is5.3 μm or less.